Hierarchical Self-Assembly and Dynamics of a Miktoarm Star chimera Composed of Poly(gamma-benzyl-L-glutamate), Polystyrene, and Polyisoprene

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dc.contributor.authorGitsas, A.en
dc.contributor.authorFloudas, G.en
dc.contributor.authorMondeshki, M.en
dc.contributor.authorLieberwirth, I.en
dc.contributor.authorSpiess, H. W.en
dc.contributor.authorIatrou, H.en
dc.contributor.authorHadjichristidis, N.en
dc.contributor.authorHirao, A.en
dc.date.accessioned2015-11-24T18:27:30Z
dc.date.available2015-11-24T18:27:30Z
dc.identifier.issn0024-9297-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16041
dc.rightsDefault Licence-
dc.subjectfunctionalized polyphenylene dendrimersen
dc.subjectcross-polarizationen
dc.subjectdiblock copolymersen
dc.subjectblock-copolymersen
dc.subjectsolid-stateen
dc.subjectmicrophase separationen
dc.subjecttriblock copolymersen
dc.subjectmolecular-dynamicsen
dc.subjectnmren
dc.subjectroden
dc.titleHierarchical Self-Assembly and Dynamics of a Miktoarm Star chimera Composed of Poly(gamma-benzyl-L-glutamate), Polystyrene, and Polyisopreneen
heal.abstractThe hierarchical self-assembly at the submicrometer, nanometer and alpha-helilcal length scales has been Studied in a miktoarm star rod-coil chimera composed of poly(gamma-benzyl-L-glutamate) (PBLG), polystyrene, and polyisoprene blocks by X-ray scattering, solid state NMR, and transmission electron microscopy. The propensity of the rod block toward alpha-helices that are further hexagonally packed gives rise to pure PBLG domains and induces the partial mixing of the two amorphous blocks. These structural results were confirmed by independent dynamic probes at the segmental and alpha-helical level by NMR and dielectric spectroscopy, respectively.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1021/Ma902631e-
heal.identifier.secondary<Go to ISI>://000274529800029-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/ma902631e-
heal.journalNameMacromoleculesen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2010-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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