Polynuclear cobalt(II/III) sulfites: Synthesis, structure, and magnetic properties of the octanuclear cluster (NH4)(11)(Li subset of[(Co4Co4III)-Co-II(SO3)(16)(NH3)(8)])center dot 10H(2)O encapsulating a lithium cation

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dc.contributor.authorChilas, G. I.en
dc.contributor.authorStylianou, M.en
dc.contributor.authorKubicki, M.en
dc.contributor.authorVaimakis, T.en
dc.contributor.authorKogerler, P.en
dc.contributor.authorKeramidas, A. D.en
dc.contributor.authorKabanos, T. A.en
dc.date.accessioned2015-11-24T16:45:10Z
dc.date.available2015-11-24T16:45:10Z
dc.identifier.issn0020-1669-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8891
dc.rightsDefault Licence-
dc.subjectcrystal-structureen
dc.subjectcomplexesen
dc.subjectligandsen
dc.subjecttrihydrateen
dc.subjectframeworken
dc.subjectcompounden
dc.subjectchainsen
dc.subjectseriesen
dc.subjectanionen
dc.subjectharden
dc.titlePolynuclear cobalt(II/III) sulfites: Synthesis, structure, and magnetic properties of the octanuclear cluster (NH4)(11)(Li subset of[(Co4Co4III)-Co-II(SO3)(16)(NH3)(8)])center dot 10H(2)O encapsulating a lithium cationen
heal.abstractPartial oxidation of an aqueous solution of (CoCl2)-Cl-II center dot 6H(2)O with (NH4)(6)[(Mo7O24)-O-VI]center dot 4H(2)O in the presence of (NH4)(2)SO3 center dot H2O and LiCl, at pH approximate to 5.3, leads to isolation of the octanuclear cluster (NH4)(11)(Li subset of[(Co4Co4III)-Co-II(SO3)(16)(NH3)(8)]center dot 10H(2)O), 1. The structure of the anion of 1 consists of a central [CO4II], almost ideal square planar unit, and a pair of symmetry-related Co-III dimers above and below the Co-4(II) plane grafting onto the tetramer by 16 bridging sulfite groups. The [Co-8(SO3)(16)(NH3)(8)](12-) cluster encapsulates a lithium cation which lies at the center of the Co4(II) square.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1021/Ic8004213-
heal.identifier.secondary<Go to ISI>://000256255000008-
heal.identifier.secondaryhttp://pubs.acs.org/doi/pdfplus/10.1021/ic8004213-
heal.journalNameInorg Chemen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2008-
heal.publisherAmerican Chemical Societyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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