Zinc complexes with tricarballylic acid and Lewis bases with zero- and two-dimensional structures
dc.contributor.author | Vlahou, I. | en |
dc.contributor.author | Kourkoumelis, N. | en |
dc.contributor.author | Michaelides, A. | en |
dc.contributor.author | Skoulika, S. | en |
dc.contributor.author | Plakatouras, J. C. | en |
dc.date.accessioned | 2015-11-24T16:52:21Z | |
dc.date.available | 2015-11-24T16:52:21Z | |
dc.identifier.issn | 0020-1693 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9869 | |
dc.rights | Default Licence | - |
dc.subject | metal-organic polymers | en |
dc.subject | tricarballylic acid | en |
dc.subject | zinc complexes | en |
dc.subject | coordination polymers | en |
dc.subject | 2d polymers | en |
dc.subject | open chain carboxylate | en |
dc.subject | metal-organic frameworks | en |
dc.subject | coordination polymers | en |
dc.subject | copper(ii) complexes | en |
dc.subject | magnetic-properties | en |
dc.subject | crystal-structures | en |
dc.subject | single-crystal | en |
dc.subject | porous solids | en |
dc.subject | ligand | en |
dc.subject | network | en |
dc.subject | design | en |
dc.title | Zinc complexes with tricarballylic acid and Lewis bases with zero- and two-dimensional structures | en |
heal.abstract | Three ternary zinc complexes of the open chain polycarboxylic acid, tricarballylic (1,2,3-propane-tricarboxylic) acid (PTCH3) have been isolated and characterized with crystallographic and physicochemical techniques. [Zn(PTCH)(phen)(H2O)](2).4H(2)O (1) (where phen = 1,10-phenanthroline) has a unique dinuclear structure, while [Zn(PTCH)(bpy)](n).3nH(2)O (2) and [Zn(PTCH)(epy)](n).4nH(2)O (3) (where bpy = 4,4'-bipyridine and epy = 1,2-bis(4-pyridine)ethane) have 2D polymeric structures. The bis-deprotonated ligand, in all three complexes, uses for coordination only two oxygen atoms, which belong to the same carboxylate in 1, and to two different carboxylates in 2 and 3. (c) 2006 Elsevier B.V. All rights reserved. | en |
heal.access | campus | - |
heal.fullTextAvailability | TRUE | - |
heal.identifier.primary | DOI 10.1016/j.ica.2006.03.001 | - |
heal.identifier.secondary | <Go to ISI>://000239475800017 | - |
heal.identifier.secondary | http://ac.els-cdn.com/S0020169306001678/1-s2.0-S0020169306001678-main.pdf?_tid=5793a31941164ed828b21dfc0273ca9d&acdnat=1333040629_61b3635a2c4fee6fd7d74a7a5922b678 | - |
heal.journalName | Inorganica Chimica Acta | en |
heal.journalType | peer reviewed | - |
heal.language | en | - |
heal.publicationDate | 2006 | - |
heal.publisher | Elsevier | en |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.type | journalArticle | - |
heal.type.el | Άρθρο Περιοδικού | el |
heal.type.en | Journal article | en |
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