Zinc complexes with tricarballylic acid and Lewis bases with zero- and two-dimensional structures

dc.contributor.authorVlahou, I.en
dc.contributor.authorKourkoumelis, N.en
dc.contributor.authorMichaelides, A.en
dc.contributor.authorSkoulika, S.en
dc.contributor.authorPlakatouras, J. C.en
dc.date.accessioned2015-11-24T16:52:21Z
dc.date.available2015-11-24T16:52:21Z
dc.identifier.issn0020-1693-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9869
dc.rightsDefault Licence-
dc.subjectmetal-organic polymersen
dc.subjecttricarballylic aciden
dc.subjectzinc complexesen
dc.subjectcoordination polymersen
dc.subject2d polymersen
dc.subjectopen chain carboxylateen
dc.subjectmetal-organic frameworksen
dc.subjectcoordination polymersen
dc.subjectcopper(ii) complexesen
dc.subjectmagnetic-propertiesen
dc.subjectcrystal-structuresen
dc.subjectsingle-crystalen
dc.subjectporous solidsen
dc.subjectliganden
dc.subjectnetworken
dc.subjectdesignen
dc.titleZinc complexes with tricarballylic acid and Lewis bases with zero- and two-dimensional structuresen
heal.abstractThree ternary zinc complexes of the open chain polycarboxylic acid, tricarballylic (1,2,3-propane-tricarboxylic) acid (PTCH3) have been isolated and characterized with crystallographic and physicochemical techniques. [Zn(PTCH)(phen)(H2O)](2).4H(2)O (1) (where phen = 1,10-phenanthroline) has a unique dinuclear structure, while [Zn(PTCH)(bpy)](n).3nH(2)O (2) and [Zn(PTCH)(epy)](n).4nH(2)O (3) (where bpy = 4,4'-bipyridine and epy = 1,2-bis(4-pyridine)ethane) have 2D polymeric structures. The bis-deprotonated ligand, in all three complexes, uses for coordination only two oxygen atoms, which belong to the same carboxylate in 1, and to two different carboxylates in 2 and 3. (c) 2006 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.ica.2006.03.001-
heal.identifier.secondary<Go to ISI>://000239475800017-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0020169306001678/1-s2.0-S0020169306001678-main.pdf?_tid=5793a31941164ed828b21dfc0273ca9d&acdnat=1333040629_61b3635a2c4fee6fd7d74a7a5922b678-
heal.journalNameInorganica Chimica Actaen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2006-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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