Mass-Spectra of Cobalt, Nickel and Copper-Complexes of Active Aldehyde Derivatives of Thiamine

dc.contributor.authorLouloudi, M.en
dc.contributor.authorHadjiliadis, N.en
dc.contributor.authorButler, I. S.en
dc.date.accessioned2015-11-24T16:41:20Z
dc.date.available2015-11-24T16:41:20Z
dc.identifier.issn0045-5105-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8405
dc.rightsDefault Licence-
dc.subjectfragment induced desorptionen
dc.subjectspectrometryen
dc.titleMass-Spectra of Cobalt, Nickel and Copper-Complexes of Active Aldehyde Derivatives of Thiamineen
heal.abstractMass spectra have been recorded for cobalt, nickel and copper complexes of the active aldehyde derivatives of thiamine, 2-(alpha-hydroxybenzyl)- and 2-(alpha-hydroxy-cyclohexylmethyl)-3-(4'-amino-2' methyl-pyrimidin-5'-yl-methyl)-5-(2-hydroxyethyl)-4-methyl)thiazole (L). The observed fragmentation patterns provide further support for the proposed MLCI3 formulations of the Co(ll) and Ni(ll) complexes, and also for oxidation of the active aldehyde derivatives of thiamine to thiochrome (L') during production of the copper complexes CuL'Cl2.H2O and [Cu(L'H)Cl][CuCl3(MeOH)].en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://A1994NV52300001-
heal.journalNameCanadian Journal of Applied Spectroscopyen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1994-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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