Covalent attachment of a biomimetic Ru-(terpy)(bpy) complex on silica surface: Catalytic potential
| dc.contributor.author | Papafotiou, F. | en |
| dc.contributor.author | Karidi, K. | en |
| dc.contributor.author | Garoufis, A. | en |
| dc.contributor.author | Louloudi, M. | en |
| dc.date.accessioned | 2015-11-24T16:55:01Z | |
| dc.date.available | 2015-11-24T16:55:01Z | |
| dc.identifier.issn | 0277-5387 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10240 | |
| dc.rights | Default Licence | - |
| dc.subject | ruthenium complex | en |
| dc.subject | grafting | en |
| dc.subject | biomimetic oxidation catalysis | en |
| dc.subject | alkene epoxidation | en |
| dc.subject | asymmetric epoxidation | en |
| dc.subject | hydrogen-peroxide | en |
| dc.subject | ruthenium catalysts | en |
| dc.subject | oxidation reactions | en |
| dc.subject | ru(iii) complexes | en |
| dc.subject | oxo complexes | en |
| dc.subject | h2o2 | en |
| dc.subject | metalloporphyrins | en |
| dc.subject | olefins | en |
| dc.title | Covalent attachment of a biomimetic Ru-(terpy)(bpy) complex on silica surface: Catalytic potential | en |
| heal.abstract | The Ru-containing modified silica [Ru-II(terpy)(4'Mebpy/4CONH(CH2)(3)SiO3/2)Cl](+)m center dot zSiO(2) has been prepared by covalent attachment on silica surface of biomimetic [Ru-II(terpy)(4-CO2H-4'-Mebpy)Cl](+). complex through the formation of a pseudo-peptide bond. The catalytic ability of bio-derived silica for alkene oxidation with (HOOBu)-Bu-t has been evaluated exhibiting significant efficiency and, in some cases, showing increased activity compared vs. the corresponding 'net' [Ru-II(terpy)(4-CO2H-4'-Mebpy)Cl](+) complex. The data supported that the covalently attached ruthenium complex preserves the catalytic behaviour of the 'net' ruthenium complex indicating that the presented grafting process was successful. (C) 2012 Elsevier Ltd. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.poly.2012.07.094 | - |
| heal.identifier.secondary | <Go to ISI>://000318747100078 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0277538712005657/1-s2.0-S0277538712005657-main.pdf?_tid=1754301a-362f-11e3-a192-00000aacb360&acdnat=1381906343_8feafe38358def8f2d95a0c6a162f8ec | - |
| heal.journalName | Polyhedron | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2013 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
Αρχεία
Φάκελος/Πακέτο αδειών
1 - 1 of 1
Φόρτωση...
- Ονομα:
- license.txt
- Μέγεθος:
- 1.74 KB
- Μορφότυπο:
- Item-specific license agreed upon to submission
- Περιγραφή: