Vibronic structure in the low lying Rydberg states of hexafluorobenzene and 1,3,5-trifluorobenzene detected by two-photon spectroscopy

dc.contributor.authorPhilis, J. G.en
dc.contributor.authorMondal, T.en
dc.contributor.authorMahapatra, S.en
dc.date.accessioned2015-11-24T18:34:39Z
dc.date.available2015-11-24T18:34:39Z
dc.identifier.issn0009-2614-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16977
dc.rightsDefault Licence-
dc.subjectthreshold ionization spectroscopyen
dc.subjectinduced fluorescence-spectraen
dc.subjectsubstituted benzene cationsen
dc.subjectjahn-teller distortionsen
dc.subjecthigher excited-statesen
dc.subjectgas-phase emissionen
dc.subjectvacuum-ultravioleten
dc.subjectabsorption-spectroscopyen
dc.subjectphotoelectron-spectrumen
dc.subjectfluorinated benzenesen
dc.titleVibronic structure in the low lying Rydberg states of hexafluorobenzene and 1,3,5-trifluorobenzene detected by two-photon spectroscopyen
heal.abstract(2+1) Resonance-enhanced multiphoton ionization (REMPI) spectra were recorded for hexafluorobenzene (HFBz) and 1,3,5-trifluorobenzene (TRFBz) using UV laser light. Vibronic structure of the Rydberg series converging to the first ionization threshold are resolved. While only one Rydberg series is observed for HFBz (region 67 500-70 820 cm(-1)), two of them are detected for TRFBz (region 66 000-69 100 cm(-1)). The resolved vibronic structures are assigned with the aid of theoretical predictions. (C) 2010 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.cplett.2010.07.007-
heal.identifier.secondary<Go to ISI>://000280554300007-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0009261410009243/1-s2.0-S0009261410009243-main.pdf?_tid=fd08fb29a4eb6ad6dced190d2bb8ca3c&acdnat=1334231896_8c67d353c40c69931b34dad2a8c25dbd-
heal.journalNameChemical Physics Lettersen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2010-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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