Synthesis and reactions of 1-aryl-2-nitropyrroles. Structural and conformational study of ethyl N-[2'-[1'-(2-nitropyrrolyl)]phenyl]-N-toluene-4-sulfonamide glycinate
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Cobb, J.
Demetropoulos, I. N.
Korakas, D.
Skoulika, S.
Varvounis, G.
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Elsevier
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peer reviewed
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Tetrahedron
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Nitration of 1-aryl(or 1-benzyl)pyrroles 1, 2 and 7 has provided the corresponding 2- and 3-nitropyrroles 3 and 5, 4 and 6, and 8 and 9 in a 1:2 ratio. Reductive cyclisation of 3 and 8, gave pyrrolo[1,2-a]quinazolines 11 and 12. and pyrrolo[1,2-b][2,4]benzodiazepine 13. respectively. A conformational study of 5 in the solid and Liquid state using X-ray diffraction analysis. molecular dynamics calculations and NMR spectroscopy is described.
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<Go to ISI>://A1996UA51000029
http://ac.els-cdn.com/0040402096000968/1-s2.0-0040402096000968-main.pdf?_tid=ab16a622-34ac-11e3-abf0-00000aab0f01&acdnat=1381740376_c14e9a89c38ed8aab5e3c921ffd8b210
http://ac.els-cdn.com/0040402096000968/1-s2.0-0040402096000968-main.pdf?_tid=ab16a622-34ac-11e3-abf0-00000aab0f01&acdnat=1381740376_c14e9a89c38ed8aab5e3c921ffd8b210
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en
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Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας