A simple method for the alkaline hydrolysis of esters

dc.contributor.authorTheodorou, V.en
dc.contributor.authorSkobridis, K.en
dc.contributor.authorTzakos, A. G.en
dc.contributor.authorRagoussis, V.en
dc.date.accessioned2015-11-24T16:38:39Z
dc.date.available2015-11-24T16:38:39Z
dc.identifier.issn0040-4039-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8066
dc.rightsDefault Licence-
dc.subjectsaponification of estersen
dc.subjectmechanismen
dc.subjectnon-aqueous conditionsen
dc.subjectmethanolysisen
dc.subjectselective enrichment of coohen
dc.subjectcarboxylic acidsen
dc.subjectalcoholsen
dc.subjecttransition-stateen
dc.subjectsaponificationen
dc.subjectconvenienten
dc.subjecthydroxideen
dc.subjectmicrowaveen
dc.subjectcarbonylen
dc.subjectacetateen
dc.subjectphaseen
dc.subjectacidsen
dc.subjectbaseen
dc.titleA simple method for the alkaline hydrolysis of estersen
heal.abstractA very mild and rapid procedure for the efficient alkaline hydrolysis of esters in non-aqueous conditions has been developed, by the use of dichloromethane/methanol (9:1) as solvent. This method conveniently provides both carboxylic acids and alcohols from the corresponding esters and sodium hydroxide in a few minutes at room temperature. A plausible reaction mechanism is proposed. (C) 2007 Elsevier Ltd. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.tetlet.2007.09.074-
heal.identifier.secondary<Go to ISI>://000252097100035-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0040403907018539/1-s2.0-S0040403907018539-main.pdf?_tid=d6cb09dc-3a30-11e3-9880-00000aacb360&acdnat=1382346898_c69e29369395a174d8b8a2b61b5b2c3d-
heal.journalNameTetrahedron Letten
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2007-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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