57Fe M?ssbauer spectroscopy studies of Sr 2Fe1-xCrxMo1-xWxO 6 double perovskite compounds

dc.contributor.authorDouvalis, A. P.en
dc.contributor.authorPanagiotopoulos, I.en
dc.contributor.authorMoukarika, A.en
dc.contributor.authorBakas, T.en
dc.contributor.authorPapaefthymiou, V.en
dc.date.accessioned2015-11-24T18:33:51Z
dc.date.available2015-11-24T18:33:51Z
dc.identifier.issn0304-3843-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16821
dc.rightsDefault Licence-
dc.subjectDouble perovskitesen
dc.subjectM?ssbauer spectroscopyen
dc.subjectSr2Fe 1-xCrxMo1-xWxO6en
dc.title57Fe M?ssbauer spectroscopy studies of Sr 2Fe1-xCrxMo1-xWxO 6 double perovskite compoundsen
heal.abstractPolycrystalline double perovskites Sr2Fe1-xCr xMo1-xWxO6 with x = 0, 0.05, 0.10, 0.15, 0.20, and 0.30 have been prepared by sold state reactions. A continuous decrease of the tetragonal unit cell parameters α and c with increasing x values is observed. The highest Curie temperature T C = 426 K is recorded for the x = 0.10 compound. 57Fe M?ssbauer spectroscopy measurements indicate a non-integral electronic configuration of ?3d 5.3 for the Fe ions at the ordered double perovskite structure for x ?0.20, which reaches ?3d5.4 for x = 0.30. Fe-Mo/W anti-site and anti-phase boundary defects are observed in all samples in equal concentrations of around 3% of the total number of Fe ions in their structure. © 2006 Springer Science+Business Media, Inc.en
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heal.fullTextAvailabilityTRUE-
heal.identifier.secondaryhttp://www.scopus.com/inward/record.url?eid=2-s2.0-33846417957&partnerID=40&md5=461b8a6e5f8e7c2b43e6ba5a05ca5255-
heal.journalNameHyperfine Interactionsen
heal.journalTypepeer reviewed-
heal.publicationDate2006-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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