Synthesis and characterization of packed mesoporous tungsteno-silicates: application to the catalytic dehydrogenation of 2-propanol
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Trens, P.
Stathopoulos, V.
Hudson, M. J.
Pomonis, P.
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Elsevier
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peer reviewed
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Applied Catalysis a-General
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Description
The synthesis of highly ordered mesoporous tungsteno-silicas in which a high percentage of tungsten is introduced into a silica framework is reported hereafter. Powder XRD and TEM have been used to characterize the materials synthesized at room temperature. The materials are shown to be homogeneous as there is no evidence for any crystalline species other than the silica framework. The pore diameter and the surface area of the materials, evaluated from the nitrogen adsorption isotherms and unit cell parameter indicate a pore diameter of about 2 nm and a surface area of 1400 m(2) g(-1) for a content of 10% tungsten. Catalyzed dehydration of 2-propanol has been investigated and the activity of the materials synthesized is significant, even for low tungsten content W-MCM-41 materials. (C) 2003 Elsevier B.V. All rights reserved.
Description
Keywords
catalysis, mesoporous materials, silica, ipa, dehydrogenation, molecular-sieve, isobutane/butene alkylation, surface, dehydration, mcm-41, clays, conversion, molybdenum, h3pw12o40, acidity
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<Go to ISI>://000221713800012
http://ac.els-cdn.com/S0926860X03010238/1-s2.0-S0926860X03010238-main.pdf?_tid=bd2ff823c1fd6b458969d9b4d57b8351&acdnat=1333036753_309872af94ad54ad458429aed653d5c6
http://ac.els-cdn.com/S0926860X03010238/1-s2.0-S0926860X03010238-main.pdf?_tid=bd2ff823c1fd6b458969d9b4d57b8351&acdnat=1333036753_309872af94ad54ad458429aed653d5c6
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en
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Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας