Synthesis, Structural Characterization, and Computational Studies of Novel Diiodine Adducts with the Heterocyclic Thioamides N-Methylbenzothiazole-2-thione and Benzimidazole-2-thione:"‰ Implications with the Mechanism of Action of Antithyroid Drugs
| dc.contributor.author | G.J. Corban, | en |
| dc.contributor.author | S.K. Hadjikakou, | en |
| dc.contributor.author | N. Hadjiliadis, | en |
| dc.contributor.author | M. Kubicki, | en |
| dc.contributor.author | E.R.t. Ticknik, | en |
| dc.contributor.author | I.S. Butler, | en |
| dc.contributor.author | E. Drougas, | en |
| dc.contributor.author | Agnie M. Kosmas | en |
| dc.date.accessioned | 2015-11-24T16:49:51Z | |
| dc.date.available | 2015-11-24T16:49:51Z | |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9536 | |
| dc.rights | Default Licence | - |
| dc.title | Synthesis, Structural Characterization, and Computational Studies of Novel Diiodine Adducts with the Heterocyclic Thioamides N-Methylbenzothiazole-2-thione and Benzimidazole-2-thione:"‰ Implications with the Mechanism of Action of Antithyroid Drugs | en |
| heal.abstract | The reaction of I2 with N-methylbenzothiazole-2-thione and benzimidazole-2-thione produced three new charge-transfer complexes. The X-ray crystal structure of {[(MBZIM)2I]+}Β·[I3-}Β·[(MBZIM)I2] reveals the cocrystallization of both a "�spoke"� and an "�iodonium"� salt. This is the first such crystal structure ever reported and may lead to the conclusion that a "�spoke"� and an iodonium salt equilibrium may also be established in solution. Useful conclusions on the mechanism of action of antithyroid drugs are drawn. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | 10.1021/ic0484396 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/abs/10.1021/ic0484396 | - |
| heal.journalName | Inorg. Chem. | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2005 | - |
| heal.publisher | American Chemical Society | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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