Preparation and spectroscopic study of 1 : 2 adducts of dimethyltin(IV)dichloride with aromatic N-oxides (IQNO, 4-ClQNO, 4-MeQNO, 6-MeOQNO and 4-PhPyNO). Crystal and molecular structure of trans-dichlorodimethyl bis(4-phenylpyridine-N-oxide)tin(IV)
| dc.contributor.author | Papadaki, H. | en |
| dc.contributor.author | Christofides, A. | en |
| dc.contributor.author | Jeffery, J. C. | en |
| dc.contributor.author | Bakas, T. | en |
| dc.date.accessioned | 2015-11-24T18:38:28Z | |
| dc.date.available | 2015-11-24T18:38:28Z | |
| dc.identifier.issn | 0095-8972 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/17342 | |
| dc.rights | Default Licence | - |
| dc.subject | crystal structure | en |
| dc.subject | quinoline-n-oxide | en |
| dc.subject | 4-phenylpyridine-n-oxide | en |
| dc.subject | complexes | en |
| dc.subject | dichloride | en |
| dc.subject | nmr | en |
| dc.title | Preparation and spectroscopic study of 1 : 2 adducts of dimethyltin(IV)dichloride with aromatic N-oxides (IQNO, 4-ClQNO, 4-MeQNO, 6-MeOQNO and 4-PhPyNO). Crystal and molecular structure of trans-dichlorodimethyl bis(4-phenylpyridine-N-oxide)tin(IV) | en |
| heal.abstract | Five adducts of general formula Me2SnCl2L2 [L = IQNO(isoquinoline-N-oxide), 4-ClQNO, 4-MeQNO, 6-MeOQNO (6-methoxyquinoline-N-oxide) and 4-PhPyNO (4-Phenylpyridine-N- oxide)] have been prepared by the addition of L to chloroform solutions of Me2SnCl2. The adducts have been characterized by analysis and spectroscopic (IR, H-1, C-13 and Mossbauer) data. Structural predictions were derived from Sn-119 NMR parameters such as (1)J(Sn-119-C-13) and (2)J(Sn-119-H-1). The single crystal diffraction study of the adduct Me2SnCl2(4-PhPyNO)(2) shows the metal to be six-coordinate in an all trans-octahedral configuration; Sn-O and Sn-Cl distances are 2.227(2) and 2.5774(9)Angstrom, respectively, and the CH3-Sn-CH3 bond angle is 180.0 degrees. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000080196400006 | - |
| heal.identifier.secondary | http://www.tandfonline.com/doi/abs/10.1080/00958979908024355 | - |
| heal.journalName | Journal of Coordination Chemistry | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1999 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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