Incorporation of fullerene derivatives into smectite clays: A new family of organic-inorganic nanocomposites
| dc.contributor.author | Gournis, D. | en |
| dc.contributor.author | Georgakilas, V. | en |
| dc.contributor.author | Karakassides, M. A. | en |
| dc.contributor.author | Bakas, T. | en |
| dc.contributor.author | Kordatos, K. | en |
| dc.contributor.author | Prato, M. | en |
| dc.contributor.author | Fanti, M. | en |
| dc.contributor.author | Zerbetto, F. | en |
| dc.date.accessioned | 2015-11-24T17:34:55Z | |
| dc.date.available | 2015-11-24T17:34:55Z | |
| dc.identifier.issn | 0002-7863 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/14053 | |
| dc.rights | Default Licence | - |
| dc.subject | raman-spectra | en |
| dc.subject | energy minimization | en |
| dc.subject | molecular-dynamics | en |
| dc.subject | force-field | en |
| dc.subject | buckminsterfullerene | en |
| dc.subject | c-60 | en |
| dc.subject | intercalation | en |
| dc.subject | macrocycles | en |
| dc.subject | confinement | en |
| dc.subject | transition | en |
| dc.title | Incorporation of fullerene derivatives into smectite clays: A new family of organic-inorganic nanocomposites | en |
| heal.abstract | Three fulleropyrrolidine derivatives, characterized by the presence of positive charges, were introduced in the interlayer space of montmorillonite. The composites were characterized by powder X-ray diffraction and differential thermal and thermogravimetric (DTA-TGA) analysis, in conjunction with FTIR, UV-Vis, Raman, and Fe-57-Mossbauer spectroscopies. Organophilic derivatives were intercalated into organically modified clays, while water-soluble fulleropyrrolidines were introduced into the clay galleries through ion exchange. The experiments, complemented by computer simulations, show that not all the clay-clay platelets are intercalated by the fullerene derivatives and that a sizable amount of charge transfer takes place between the host and the guests. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Ja049237b | - |
| heal.identifier.secondary | <Go to ISI>://000222612600044 | - |
| heal.journalName | J Am Chem Soc | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2004 | - |
| heal.publisher | American Chemical Society | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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