Monte Carlo simulation of star/linear and star/star blends with chemically identical monomers

dc.contributor.authorTheodorakis, P. E.en
dc.contributor.authorAvgeropoulos, A.en
dc.contributor.authorFreire, J. J.en
dc.contributor.authorKosmas, M.en
dc.contributor.authorVlahos, C.en
dc.date.accessioned2015-11-24T16:42:17Z
dc.date.available2015-11-24T16:42:17Z
dc.identifier.issn0953-8984-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8530
dc.rightsDefault Licence-
dc.subjectthermodynamic interaction parameteren
dc.subjectbond-fluctuation modelen
dc.subjectpolymer mixturesen
dc.subjectstaren
dc.subjectchainen
dc.subjectpolybutadieneen
dc.subjecthomopolymersen
dc.subjectarchitectureen
dc.subjectmiscibilityen
dc.subjectdimensionsen
dc.titleMonte Carlo simulation of star/linear and star/star blends with chemically identical monomersen
heal.abstractThe effects of chain size and architectural asymmetry on the miscibility of blends with chemically identical monomers, differing only in their molecular weight and architecture, are studied via Monte Carlo simulation by using the bond fluctuation model. Namely, we consider blends composed of linear/linear, star/linear and star/star chains. We found that linear/linear blends are more miscible than the corresponding star/star mixtures. In star/linear blends, the increase in the volume fraction of the star chains increases the miscibility. For both star/linear and star/star blends, the miscibility decreases with the increase in star functionality. When we increase the molecular weight of linear chains of star/linear mixtures the miscibility decreases. Our findings are compared with recent analytical and experimental results.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1088/0953-8984/19/46/466111-
heal.identifier.secondary<Go to ISI>://000250689100013-
heal.identifier.secondaryhttp://iopscience.iop.org/0953-8984/19/46/466111/pdf/0953-8984_19_46_466111.pdf-
heal.journalNameJournal of Physics-Condensed Matteren
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2007-
heal.publisherInstitute of Physicsen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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