Structural and spectroscopic characterization of a cationic aquanitrato copper(II) complex with the tetradentate Schiff-base ligand N,N '-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine
| dc.contributor.author | Gourbatsis, S. | en |
| dc.contributor.author | Hadjiliadis, N. | en |
| dc.contributor.author | Perlepes, S. P. | en |
| dc.contributor.author | Garoufis, A. | en |
| dc.contributor.author | Butler, I. S. | en |
| dc.date.accessioned | 2015-11-24T16:47:58Z | |
| dc.date.available | 2015-11-24T16:47:58Z | |
| dc.identifier.issn | 0340-4285 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9264 | |
| dc.rights | Default Licence | - |
| dc.subject | superoxide-dismutase | en |
| dc.subject | cu2zn2sod model | en |
| dc.subject | coordination chemistry | en |
| dc.subject | crystal-structures | en |
| dc.subject | nitrate | en |
| dc.title | Structural and spectroscopic characterization of a cationic aquanitrato copper(II) complex with the tetradentate Schiff-base ligand N,N '-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine | en |
| heal.abstract | Cu(NO3)(2). 3H(2)O reacts with 1 equiv. of the tetradentate Schiff base N,N'-bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine (LA) in refluxing acetone to yield the [CuLA(ONO2)(H2O)](NO3) complex in ca. 80% yield. The structure of this salt has been determined by single-crystal X-ray crystallography. The copper is six-coordinated with the L-A ligand in the equatorial plane and weakly bonded aqua and nitrate ligands above and below this plane. The complex cation is hydrogen-bonded to the nitrate counter-ion. The complex was also characterized by elemental analyses, molar conductivity, room-temperature magnetic susceptibility and spectroscopic (i.r., far-i.r., u.v.-vis, e.s.r.) studies. The data are discussed in terms of the nature of bonding and the known structure. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000077821300013 | - |
| heal.identifier.secondary | http://www.springerlink.com/content/u563510067837r60/fulltext.pdf | - |
| heal.journalName | Transition Metal Chemistry | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1998 | - |
| heal.publisher | Springer Verlag (Germany) | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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