Aqueous phototransformation of zinc pyrithione - Degradation kinetics and byproduct identification by liquid chromatography-atmospheric pressure chemical ionisation mass spectrometry
Φόρτωση...
Ημερομηνία
Συγγραφείς
Sakkas, V. A.
Shibata, K.
Yamaguchi, Y.
Sugasawa, S.
Albanis, T.
Τίτλος Εφημερίδας
Περιοδικό ISSN
Τίτλος τόμου
Εκδότης
Elsevier
Περίληψη
Τύπος
Είδος δημοσίευσης σε συνέδριο
Είδος περιοδικού
peer reviewed
Είδος εκπαιδευτικού υλικού
Όνομα συνεδρίου
Όνομα περιοδικού
Journal of Chromatography A
Όνομα βιβλίου
Σειρά βιβλίου
Έκδοση βιβλίου
Συμπληρωματικός/δευτερεύων τίτλος
Περιγραφή
The photochemical behavior of the antifouling agent zinc pyrithione (ZnPT) was studied in aqueous media of different composition under simulated solar irradiation using a xenon light source. The influence of important constituents of natural water (dissolved organic matter and nitrate) was also examined using a multivariate kinetic model. It was found that photodegradation proceeds via a pseudo first-order reaction. Kinetic experiments were monitored by LC-MS and photolytic half-lives ranging between 9.2 and 15.1 min have been observed. The increasing concentration of dissolved organic matter (DOM) accelerates the photolysis reaction, while the effect of nitrate ions was also positive since it increased the degradation rate, but to a lesser extent. Irradiation of the aqueous ZnPT solutions gave rise to several transformation products that were isolated by means of solid-phase extraction using poly(styrene-divinylbenzene) extraction disks. These byproducts were identified using liquid chromatography-atmospheric pressure chemical ionisation mass spectrometry. Besides 2-pyridinesulfonic-acid, other degradation products formed included pyridine-N-oxide, 2-mercaptopyridine, 2,2'-dithiobis(pyridine-N-oxide), 2,2-dipyridyl disulfide and the pyridine/pyrithione mixed disulfide, 2,2'-dithiobispyridine mono-N-oxide (PPMD). (c) 2007 Elsevier B.V. All rights reserved.
Περιγραφή
Λέξεις-κλειδιά
photodegradation, zinc pyrithione, dissolved organic matter, fate, dissolved organic-matter, paint booster biocides, natural-waters, environmental fate, photolysis, behavior, nitrate
Θεματική κατηγορία
Παραπομπή
Σύνδεσμος
<Go to ISI>://000245004100003
http://ac.els-cdn.com/S0021967307000544/1-s2.0-S0021967307000544-main.pdf?_tid=8c5828646c950426dc113fe267062dc8&acdnat=1333023418_ab7ca9c52affd5a181045479223c3f9e
http://ac.els-cdn.com/S0021967307000544/1-s2.0-S0021967307000544-main.pdf?_tid=8c5828646c950426dc113fe267062dc8&acdnat=1333023418_ab7ca9c52affd5a181045479223c3f9e
Γλώσσα
en
Εκδίδον τμήμα/τομέας
Όνομα επιβλέποντος
Εξεταστική επιτροπή
Γενική Περιγραφή / Σχόλια
Ίδρυμα και Σχολή/Τμήμα του υποβάλλοντος
Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας