Structure of bis(2-acetylpyridine 3-hexamethyleneiminylthiosemicarbazonato) palladium(II), a potential antitumor complex
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Kovala-Demertzi, D.
Demertzis, M. A.
Miller, J. R.
Frampton, C. S.
Jasinski, J. P.
West, D. X.
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peer reviewed
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J Inorg Biochem
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The crystal structure of the potential antitumor complex bis(2-acetyppyridine 3-hexamethyleneiminylthiosemicarbazonato)palladium(II) has been solved. The palladium(H) atom is in a square planar environment surrounded by two cis nitrogen atoms and two cis sulfur atoms. The ligands are not equivalent, one being tridentate with (N,N,S) donation, the other being monodentate using only the sulfur atom to coordinate to the metal. The tridentate ligand shows a Z, E, Z configuration while the monodentate ligand shows an E, E, Z. Intermolecular hydrogen bonds stabilize the structure, while the crystal packing is determined by Pd-C, Pd-pi, C-H-pi and pi-pi interactions. (C) 2002 Elsevier Science Inc. All rights reserved.
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palladium(ii) complexes, thiosemicarbazonato complexes, crystal structure, antitumor activity, spectral properties, 2-acetylpyridine, thiosemicarbazone, derivatives
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<Go to ISI>://000179169900007
http://ac.els-cdn.com/S0162013402004932/1-s2.0-S0162013402004932-main.pdf?_tid=e50b28af1c0440653756a22530fac94c&acdnat=1333028741_836a662182c3e31621bb8aec22f0bc8f
http://ac.els-cdn.com/S0162013402004932/1-s2.0-S0162013402004932-main.pdf?_tid=e50b28af1c0440653756a22530fac94c&acdnat=1333028741_836a662182c3e31621bb8aec22f0bc8f
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en
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Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας