Internal rotation of the methyl group in the S-0 and S-1 (3s Rydberg) electronic states of N-methylpyrrole
| dc.contributor.author | Philis, J. G. | en |
| dc.date.accessioned | 2015-11-24T18:26:46Z | |
| dc.date.available | 2015-11-24T18:26:46Z | |
| dc.identifier.issn | 0009-2614 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/15948 | |
| dc.rights | Default Licence | - |
| dc.subject | p-fluorotoluene | en |
| dc.subject | excited-states | en |
| dc.subject | spectra | en |
| dc.subject | molecules | en |
| dc.subject | toluene | en |
| dc.subject | jet | en |
| dc.subject | spectroscopy | en |
| dc.subject | conformation | en |
| dc.subject | phenylsilane | en |
| dc.subject | ionization | en |
| dc.title | Internal rotation of the methyl group in the S-0 and S-1 (3s Rydberg) electronic states of N-methylpyrrole | en |
| heal.abstract | The one-photon and two-photon REMPI spectra of the ((1)A(2))S-1 <-- ((1)A(1))S-o Rydberg transition of jet-cooled N-methylpyrrole have been investigated, The transition is one-photon symmetry forbidden and a number of well-resolved low-frequency bands are present in the one-photon resonant MPI spectrum, on both sides of the absent origin, These spectral features. assigned to pure torsional transitions of the methyl group, gain intensity from an electronic motion-internal rotation coupling mechanism. The analysis afforded the potentials for the internal rotation of the methyl group in both states: V-6(n) = -45 cm(-1), B-n = 5.37 cm(-1) for the ground state and V (n)(6) = 17 cm(-1). B' = 5.24 cm(-1) for the S-1 excited state. (C) 2002 Elsevier Science B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000173918400013 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S000926140200012X/1-s2.0-S000926140200012X-main.pdf?_tid=3590279d5a3a973aaa55e6ae1a11d2e7&acdnat=1334231811_be3962a6130322bc906f7632e4062727 | - |
| heal.journalName | Chemical Physics Letters | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2002 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
Αρχεία
Φάκελος/Πακέτο αδειών
1 - 1 of 1
Φόρτωση...
- Ονομα:
- license.txt
- Μέγεθος:
- 1.74 KB
- Μορφότυπο:
- Item-specific license agreed upon to submission
- Περιγραφή: