Sulfur Dioxide Insertion Reactions Into Metal Alkoxide Bonds: Synthesis and Crystal Structure of catena-Bis(methylsulfito)bis(methanol)calcium; a One-dimensional Polymer Based on Eight-Coordinate Calcium Ions

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dc.contributor.authorV. -C. Arunasalam,en
dc.contributor.authorI. Baxter,en
dc.contributor.authorM. B. Hursthouse,en
dc.contributor.authorK. M. A. Malik,en
dc.contributor.authorD. M. P. Mingos,en
dc.contributor.authorJ. C. Plakatourasen
dc.date.accessioned2015-11-24T16:48:46Z
dc.date.available2015-11-24T16:48:46Z
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9362
dc.rightsDefault Licence-
dc.titleSulfur Dioxide Insertion Reactions Into Metal Alkoxide Bonds: Synthesis and Crystal Structure of catena-Bis(methylsulfito)bis(methanol)calcium; a One-dimensional Polymer Based on Eight-Coordinate Calcium Ionsen
heal.abstractThe reaction of So2(g) with a suspension of [M(OMe)2]n(M = Mg and Ca) in methanol yields the crystalline compounds, [M(O2SOMe)2(MeOH)2]�(M = Mg 1, Ca 2); the insertion reaction is of high yield and the X-ray crystal structure of complex 2 reveals that it is a chain polymer with eight-coordinated CaII ions and the methylsulfito anions acting as both chelating and bridging ligands.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primary10.1039/C39940002695-
heal.identifier.secondaryhttp://pubs.rsc.org/en/content/articlelanding/1994/C3/c39940002695#!divAbstract-
heal.journalNameJ. Chem. Soc., Chem. Commun.en
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1994-
heal.publisherRoyal Society of Chemistryen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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