Brownian Dynamics Simulations on Self-Assembly Behavior of H-Shaped Copolymers and Terpolymers.
| dc.contributor.author | Moultos, O. | en |
| dc.contributor.author | Gergidis, L. N. | en |
| dc.contributor.author | Vlahos, C. | en |
| dc.date.accessioned | 2015-11-24T16:53:18Z | |
| dc.date.available | 2015-11-24T16:53:18Z | |
| dc.identifier.issn | 0024-9297 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9997 | |
| dc.rights | Default Licence | - |
| dc.subject | molecular-dynamics | en |
| dc.subject | micellization behavior | en |
| dc.subject | block-copolymers | en |
| dc.subject | diblock copolymers | en |
| dc.subject | selective solvent | en |
| dc.subject | model | en |
| dc.subject | micelles | en |
| dc.subject | pi | en |
| dc.subject | architecture | en |
| dc.subject | amphiphiles | en |
| dc.title | Brownian Dynamics Simulations on Self-Assembly Behavior of H-Shaped Copolymers and Terpolymers. | en |
| heal.abstract | The micellization behavior of the H-shaped copolymers and terpolymers is studied by means of Brownian dynamics simulations. The critical micelle concentration, the micelle size distribution and the shape of micelles are examined as a function of the mass fraction of the solvophobic units. Three regimes were found. H-shaped copolymers with solvophobic content >= 50% form micelles with preferential aggregation number. Those with content << 10% do not aggregate at the simulation temperature. For the remaining content values the formation of micelles exhibits a wide variation of aggregation numbers. These regimes are in qualitative agreement with the experimental findings. H-shaped terpolymers form micelles with larger aggregation number than the respective H-shaped copolymers. Janus-like micelles or micelles with multi-compartment coronas are obtained. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Ma101138w | - |
| heal.identifier.secondary | <Go to ISI>://000280855000046 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/ma101138w | - |
| heal.journalName | Macromolecules | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2010 | - |
| heal.publisher | American Chemical Society | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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