Self-assembly of dialkyltin(IV) moieties and a thiosemicarbone to a trinuclear macrocycle and the unprecedented formation of two pseudo-polymorphs with different cavities

dc.contributor.authorD. Kovala-Demertzi,en
dc.contributor.authorJ. Wiecek,en
dc.contributor.authorJ. C. Plakatouras,en
dc.contributor.authorZ. Ciuniken
dc.date.accessioned2015-11-24T16:46:52Z
dc.date.available2015-11-24T16:46:52Z
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9114
dc.rightsDefault Licence-
dc.titleSelf-assembly of dialkyltin(IV) moieties and a thiosemicarbone to a trinuclear macrocycle and the unprecedented formation of two pseudo-polymorphs with different cavitiesen
heal.abstractThe reaction of dimethyltin(IV)oxide with pyruvic acid thiosemicarbazone (H2pt) and subsequent recrystallization from THF leads to the formation two pseudo-polymorphs based on triangular [(CH3)2Sn(pt)]3 units; one of them [(CH3)2Sn(pt)]3.3THF (1) with tubular cavities while the other [(CH3)2Sn(pt)]3.1.5THF (2) is a H-bonded 3D network with truncated tetrahedral cavities.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primary10.1039/b809216h-
heal.identifier.secondaryhttp://pubs.rsc.org/en/content/articlelanding/2008/ce/b809216h#!divAbstract-
heal.journalNameCrystengcommen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2008-
heal.publisherRoyal Society of Chemistryen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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