Surface-functionalized nanoparticles with liquid-like behavior: The role of the constituent components

dc.contributor.authorBourlinos, A. B.en
dc.contributor.authorGiannelis, E. P.en
dc.contributor.authorZhang, Q.en
dc.contributor.authorArcher, L. A.en
dc.contributor.authorFloudas, G.en
dc.contributor.authorFytas, G.en
dc.date.accessioned2015-11-24T18:34:30Z
dc.date.available2015-11-24T18:34:30Z
dc.identifier.issn1292-8941-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/16950
dc.rightsDefault Licence-
dc.subject89en
dc.subject75en
dc.subject-k complex systemsen
dc.subject83en
dc.subject10en
dc.subjecttv structural and phase changesen
dc.subject62en
dc.subject25en
dc.subject+g mechanical properties of nanoscale materialsen
dc.subjectthermal-conductivityen
dc.subjectionic liquidsen
dc.subjectnanotube suspensionsen
dc.subjectdynamicsen
dc.subjectcopolymersen
dc.subjectnanofluidsen
dc.subjectnanostructuresen
dc.subjectpolymersen
dc.subjectoxideen
dc.titleSurface-functionalized nanoparticles with liquid-like behavior: The role of the constituent componentsen
heal.abstractIonically modified silica nanoparticles with large counter anions (sulfonate, isostearate) at two silica volume fractions (13 and 27%) form a viscous fluid and a glass but not crystalline solids. Dielectric spectroscopy, Brillouin scattering and shear rheometry were employed to investigate these new nanoparticle-based fluids. The glass transition temperature and hence the local dynamics are governed by the large counter anions, whereas the flow properties can be controlled by the spatial correlation between the nanoparticles, e.g. by tuning the volume fraction of hard cores and local interactions between segments in the soft corona. Liquid-like ordering of the cores was revealed by X-ray scattering and found to influence significantly the macroscopic flow properties of these salts.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1140/epje/i2006-10007-3-
heal.identifier.secondary<Go to ISI>://000237974900013-
heal.identifier.secondaryhttp://www.springerlink.com/content/a80h427516137l52/fulltext.pdf-
heal.journalNameEuropean Physical Journal Een
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2006-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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