Torsional features in the (3s)S-1 <- S-0 transition of N-methylpyrrole and C4D4NCH3
| dc.contributor.author | Philis, J. G. | en |
| dc.date.accessioned | 2015-11-24T18:26:43Z | |
| dc.date.available | 2015-11-24T18:26:43Z | |
| dc.identifier.issn | 0022-2860 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/15939 | |
| dc.rights | Default Licence | - |
| dc.subject | n-methylpyrrole | en |
| dc.subject | methyl torsional transitions | en |
| dc.subject | rempi | en |
| dc.subject | electronic excitation | en |
| dc.subject | pyrrole | en |
| dc.subject | furan | en |
| dc.subject | states | en |
| dc.subject | cyclopentadiene | en |
| dc.subject | spectra | en |
| dc.subject | absorption | en |
| dc.subject | molecules | en |
| dc.subject | band | en |
| dc.subject | s-0 | en |
| dc.title | Torsional features in the (3s)S-1 <- S-0 transition of N-methylpyrrole and C4D4NCH3 | en |
| heal.abstract | The one-photon and two-photon S-1 <-- S-0 REMPI spectra of jet-cooled N-methylpyrrole-ring-d(4) (C4D4NCH3, NMPd4) were studied and compared to the corresponding spectra of N-methylpyrrole (C4H4NCH3, NMP). This electronic transition is the electric dipole forbidden 3sA(2) <-- A(1) Rydberg excitation. The transition is allowed in two-photon spectroscopy and the origin was found in the two-photon spectra at 41,193 and 42,015 cm(-1) for NMP and NMPd4, respectively. Exactly the same low-frequency pattern is present close to the absent origin in the one-photon spectra of NMP and NMPd4. The assignment of these features to methyl internal rotational transitions is confirmed. (C) 2003 Elsevier Science B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000183424200075 | - |
| heal.journalName | Journal of Molecular Structure | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2003 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
Αρχεία
Φάκελος/Πακέτο αδειών
1 - 1 of 1
Φόρτωση...
- Ονομα:
- license.txt
- Μέγεθος:
- 1.74 KB
- Μορφότυπο:
- Item-specific license agreed upon to submission
- Περιγραφή: