An unusual hydrogen-bonded network associated with metal-organic chains: Structure and crystal packing of the coordination polymer [Cd(terephthalate)(H2O)(3)]center dot 4H(2)O
| dc.contributor.author | Michaelides, O. A. | en |
| dc.contributor.author | Tsaousis, D. | en |
| dc.contributor.author | Skoulika, S. | en |
| dc.contributor.author | Raptopoulou, C. P. | en |
| dc.contributor.author | Terzis, A. | en |
| dc.date.accessioned | 2015-11-24T16:49:08Z | |
| dc.date.available | 2015-11-24T16:49:08Z | |
| dc.identifier.issn | 0108-7681 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9433 | |
| dc.rights | Default Licence | - |
| dc.subject | complexes | en |
| dc.subject | water | en |
| dc.subject | topography | en |
| dc.subject | ligands | en |
| dc.subject | solids | en |
| dc.subject | acid | en |
| dc.title | An unusual hydrogen-bonded network associated with metal-organic chains: Structure and crystal packing of the coordination polymer [Cd(terephthalate)(H2O)(3)]center dot 4H(2)O | en |
| heal.abstract | Single crystals of [Cd(terephthalate) (H2O)(3)].4H(2)O (1), triaquo(1,4-benzenecarboxylato-kappa O)cadmium tetrahydrate, are grown in a silica gel column. Crystal structure analysis shows that (1) is a polymer with metal-organic chains stacked along the a axis forming layers parallel to the ab plane. These layers are linked by an unusual hydrogen-bonded network formed by the water molecules (both 'free' and coordinated ones) and the carboxylate O atoms. This network comprises tridymite-like O-8 cages which 'propagate' in the direction of the a axis, mimicking the way they 'propagate' along the c axis in hexagonal ice. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | 10.1107/S0108768197020107 | - |
| heal.identifier.secondary | <Go to ISI>://000076689700018 | - |
| heal.journalName | Acta Crystallographica Section B-Structural Science | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1998 | - |
| heal.publisher | Munksgaard Int Publ Ltd. | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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