Gas chromatographic determination of carbonyl compounds in biological and oil samples by headspace single-drop microextraction with in-drop derivatisation
| dc.contributor.author | Fiamegos, Y. C. | en |
| dc.contributor.author | Stalikas, C. D. | en |
| dc.date.accessioned | 2015-11-24T16:38:21Z | |
| dc.date.available | 2015-11-24T16:38:21Z | |
| dc.identifier.issn | 0003-2670 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8032 | |
| dc.rights | Default Licence | - |
| dc.subject | headspace single-drop | en |
| dc.subject | microextraction 2,4,6-trichlorophenylhydrazine | en |
| dc.subject | aldehydes oil | en |
| dc.subject | plasma urine | en |
| dc.subject | solid-phase microextraction | en |
| dc.subject | on-fiber derivatization | en |
| dc.subject | electron-capture detection | en |
| dc.subject | mass-selective detection | en |
| dc.subject | lipid-peroxidation | en |
| dc.subject | human blood | en |
| dc.subject | thermal-desorption | en |
| dc.subject | fatty-acids | en |
| dc.subject | aldehydes | en |
| dc.subject | spectrometry | en |
| dc.title | Gas chromatographic determination of carbonyl compounds in biological and oil samples by headspace single-drop microextraction with in-drop derivatisation | en |
| heal.abstract | A suitable method for the gas chromatographic determination of 10 characteristic carbonyls in biological and oil samples based on the in-drop formation of hydrazones by using 2,4,6-trichlorophenylhydrazine (TCPH), has been developed. The derivatisation-extraction procedure was optimized separately for aqueous and oil samples with respect to the appropriate organic drop solvent, drop volume, in-drop TCPH concentration, sample stirring rate, temperature during single-drop microextraction (SDME), reaction time and headspace-to-sample volume ratio. The optimization showed differentiation of optimum values between the studied matrices. The limits of detection were found to range from 0.001 to 0.003 mu g mL(-1) for the aqueous biological samples and from 0.06 to 0.20 mu g mL(-1) for the oil samples. The limits of quantification were in the range of 0.003-0.010 mu g mL(-1) and 0.020-0.059 mu g mL(-1) for aqueous and oil samples, respectively The overall relative standard deviations of the within-day repeatability and between-day reproducibility were < 4.4% and < 8.2% for the aqueous biological samples and < 3.9% and < 7.4% for the oxidized oil samples. (c) 2008 Elsevier B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.aca.2007.12.042 | - |
| heal.identifier.secondary | <Go to ISI>://000253616500005 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0003267008000299/1-s2.0-S0003267008000299-main.pdf?_tid=bc649cd6541b25d91d3f8d6c13086de9&acdnat=1333040770_a324c5491e366865b8d2df111caf3e78 | - |
| heal.journalName | Analytica Chimica Acta | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2008 | - |
| heal.publisher | Elsevier | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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