Prussian Blue Analogues of Reduced Dimensionality

dc.contributor.authorGengler, R. Y. N.en
dc.contributor.authorToma, L. M.en
dc.contributor.authorPardo, E.en
dc.contributor.authorLloret, F.en
dc.contributor.authorKe, X. X.en
dc.contributor.authorVan Tendeloo, G.en
dc.contributor.authorGournis, D.en
dc.contributor.authorRudolf, P.en
dc.date.accessioned2015-11-24T17:37:39Z
dc.date.available2015-11-24T17:37:39Z
dc.identifier.issn1613-6810-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14390
dc.rightsDefault Licence-
dc.subjectlangmuir-blodgett-filmsen
dc.subjectsingle-chain magnetsen
dc.subjectsquare grid networken
dc.subjectthin-filmsen
dc.subjecthybrid filmsen
dc.subjectphotoinduced magnetizationen
dc.subjectordering temperatureen
dc.subjectcrystal-structuresen
dc.subjectiron(ii) complexen
dc.subjectdegrees-cen
dc.titlePrussian Blue Analogues of Reduced Dimensionalityen
heal.abstractMixed-valence polycyanides (Prussian Blue analogues) possess a rich palette of properties spanning from room-temperature ferromagnetism to zero thermal expansion, which can be tuned by chemical modifications or the application of external stimuli (temperature, pressure, light irradiation). While molecule-based materials can combine physical and chemical properties associated with molecular-scale building blocks, their successful integration into real devices depends primarily on higher-order properties such as crystal size, shape, morphology, and organization. Herein a study of a new reduced-dimensionality system based on Prussian Blue analogues (PBAs) is presented. The system is built up by means of a modified Langmuir-Blodgett technique, where the PBA is synthesized from precursors in a self-limited reaction on a clay mineral surface. The focus of this work is understanding the magnetic properties of the PBAs in different periodic, low-dimensional arrangements, and the influence of the "on surface" synthesis on the final properties and dimensionality of the system.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1002/smll.201200517-
heal.identifier.secondary<Go to ISI>://000307390300012-
heal.journalNameSmallen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2012-
heal.publisherWileyen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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