Chemical Sensor Materials Based on Clathrates. Inclusion Compounds of 2,2"™-Bis(9-Hydroxy-9-Fluorenyl) Biphenyl with Organic Solvent Vapors for Coating Applications in Mass Sensitive Devices
dc.contributor.author | K. Buhlmann, | en |
dc.contributor.author | J. Reinbold, | en |
dc.contributor.author | K. Cammann, | en |
dc.contributor.author | K. Skobridis, | en |
dc.contributor.author | A. Wierig | en |
dc.contributor.author | E. Weber | en |
dc.date.accessioned | 2015-11-24T16:53:43Z | |
dc.date.available | 2015-11-24T16:53:43Z | |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10059 | |
dc.rights | Default Licence | - |
dc.title | Chemical Sensor Materials Based on Clathrates. Inclusion Compounds of 2,2"™-Bis(9-Hydroxy-9-Fluorenyl) Biphenyl with Organic Solvent Vapors for Coating Applications in Mass Sensitive Devices | en |
heal.abstract | The solid host compound 2,2'-bis (9-hydroxy-9-fluorenyl)biphenyl 1 enclathrates organic solvent vapours such as acetone, methanol and 1-butanol to give stoichiometric inclusion complexes. Using differential scanning calorimetry (DSC), desorption enthalpies were estimated to 10-20 k J/tool, indicating weak host-guest interactions. Clathrate formations with acetone and methanol are reversible and reproducible, and show a dependence of the mass increase on the solvent concentration in a gas flow. The application of host compound 1 as receptor layer can be important for the future developmen of mass sensors for the determination of organic solvent vapours. | en |
heal.access | campus | - |
heal.fullTextAvailability | TRUE | - |
heal.identifier.secondary | http://download.springer.com/static/pdf/130/art%253A10.1007%252FBF00323929.pdf?auth66=1390645007_5e11c1764bc8b94f43b9eda89bc60373&ext=.pdf | - |
heal.journalName | Fresen. J. Anal. Chem. | en |
heal.journalType | peer reviewed | - |
heal.language | en | - |
heal.publicationDate | 1994 | - |
heal.publisher | Springer-Verlag | en |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.type | journalArticle | - |
heal.type.el | Άρθρο Περιοδικού | el |
heal.type.en | Journal article | en |
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