Chemical Sensor Materials Based on Clathrates. Inclusion Compounds of 2,2"™-Bis(9-Hydroxy-9-Fluorenyl) Biphenyl with Organic Solvent Vapors for Coating Applications in Mass Sensitive Devices

dc.contributor.authorK. Buhlmann,en
dc.contributor.authorJ. Reinbold,en
dc.contributor.authorK. Cammann,en
dc.contributor.authorK. Skobridis,en
dc.contributor.authorA. Wierigen
dc.contributor.authorE. Weberen
dc.date.accessioned2015-11-24T16:53:43Z
dc.date.available2015-11-24T16:53:43Z
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10059
dc.rightsDefault Licence-
dc.titleChemical Sensor Materials Based on Clathrates. Inclusion Compounds of 2,2"™-Bis(9-Hydroxy-9-Fluorenyl) Biphenyl with Organic Solvent Vapors for Coating Applications in Mass Sensitive Devicesen
heal.abstractThe solid host compound 2,2'-bis (9-hydroxy-9-fluorenyl)biphenyl 1 enclathrates organic solvent vapours such as acetone, methanol and 1-butanol to give stoichiometric inclusion complexes. Using differential scanning calorimetry (DSC), desorption enthalpies were estimated to 10-20 k J/tool, indicating weak host-guest interactions. Clathrate formations with acetone and methanol are reversible and reproducible, and show a dependence of the mass increase on the solvent concentration in a gas flow. The application of host compound 1 as receptor layer can be important for the future developmen of mass sensors for the determination of organic solvent vapours.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondaryhttp://download.springer.com/static/pdf/130/art%253A10.1007%252FBF00323929.pdf?auth66=1390645007_5e11c1764bc8b94f43b9eda89bc60373&ext=.pdf-
heal.journalNameFresen. J. Anal. Chem.en
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1994-
heal.publisherSpringer-Verlagen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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