Identification of two allylbenzene conformers by one- and two-photon resonant multiphoton ionization spectroscopy in a supersonic jet
| dc.contributor.author | Philis, J. G. | en |
| dc.contributor.author | Kosmidis, C. | en |
| dc.date.accessioned | 2015-11-24T18:27:12Z | |
| dc.date.available | 2015-11-24T18:27:12Z | |
| dc.identifier.issn | 0022-2852 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/16002 | |
| dc.rights | Default Licence | - |
| dc.subject | minimum energy conformations | en |
| dc.subject | internal-rotation | en |
| dc.subject | vibrational-relaxation | en |
| dc.subject | 2-photon spectroscopy | en |
| dc.subject | aromatic-molecules | en |
| dc.subject | p-fluorotoluene | en |
| dc.subject | selection-rules | en |
| dc.subject | spectra | en |
| dc.subject | phenylsilane | en |
| dc.subject | isomers | en |
| dc.title | Identification of two allylbenzene conformers by one- and two-photon resonant multiphoton ionization spectroscopy in a supersonic jet | en |
| heal.abstract | Two allylbenzene conformers have been identified using resonance-enhanced multiphoton ionization spectroscopy (REMPI) in a supersonic jet expansion. Their existence has been confirmed by the vibrational analysis of the S-1 <-- S-0 pi pi* transition, recorded under (1 + 1) and (2 + 2) REMPI schemes and by the intensity variation of their spectra under various expansion conditions. The conformer with higher excitation energy shows strong dependence on the terminal beam temperature, which is consistent with a shallow potential energy well as predicted by theory. The relative abundance of the two conformers and the frequency values of several vibrational modes in their lower excited singlet electronic state S, have been determined. (C) 1997 Academic Press. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://A1997WH31800009 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0022285296971726/1-s2.0-S0022285296971726-main.pdf?_tid=604accb8e34989ec6b6a25d334daa5a4&acdnat=1334231871_1d5b90821f82b4df7ed7a22b3c436676 | - |
| heal.journalName | Journal of Molecular Spectroscopy | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 1997 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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