New Non-Oxo Vanadium-(Iv) and Vanadium-(V) Complexes

dc.contributor.author	Kabanos, T. A.	en
dc.contributor.author	Slawin, A. M. Z.	en
dc.contributor.author	Williams, D. J.	en
dc.contributor.author	Woollins, J. D.	en
dc.date.accessioned	2015-11-24T16:42:39Z
dc.date.available	2015-11-24T16:42:39Z
dc.identifier.issn	0300-9246	-
dc.identifier.uri	https://olympias.lib.uoi.gr/jspui/handle/123456789/8578
dc.rights	Default Licence	-
dc.subject	stereochemistry	en
dc.title	New Non-Oxo Vanadium-(Iv) and Vanadium-(V) Complexes	en
heal.abstract	Sequential addition of 1,10-phenanthroline (phen) or 2,2'-bipyridine (bipy) followed by 3,5-di-tert-butylcatechol (H2dtbc) to oxobis(pentane-2,4-dionato)vanadium(IV) yields [V(dtbc)2L] (L = phen or bipy) which can be oxidised using Ag[SbF6] to give [V(dtbc)2L][SbF6]. The new compounds have been characterised by microanalyses, IR, UV/VIS, V-51 NMR spectroscopy, magnetic susceptibility measurements and electrochemical studies. The X-ray structure of [V(dtbc)2(bipy)] is reported and compared with those of [V(dtbc)2(phen)] and [V(dtbc)2(phen)][SbF6].	en
heal.access	campus	-
heal.fullTextAvailability	TRUE	-
heal.identifier.secondary	<Go to ISI>://A1992HQ62000015	-
heal.journalName	Journal of the Chemical Society-Dalton Transactions	en
heal.journalType	peer reviewed	-
heal.language	en	-
heal.publicationDate	1992	-
heal.recordProvider	Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας	el
heal.type	journalArticle	-
heal.type.el	Άρθρο Περιοδικού	el
heal.type.en	Journal article	en

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