Use of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn2SnS4(N2H4)(2)]
| dc.contributor.author | Manos, M. J. | en |
| dc.contributor.author | Kanatzidis, M. G. | en |
| dc.date.accessioned | 2015-11-24T16:52:05Z | |
| dc.date.available | 2015-11-24T16:52:05Z | |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9826 | |
| dc.rights | Default Licence | - |
| dc.subject | nonlinear-optical response | en |
| dc.subject | clusters | en |
| dc.subject | sulfide | en |
| dc.subject | polychalcogenide | en |
| dc.subject | semiconductors | en |
| dc.subject | chemistry | en |
| dc.subject | aerogels | en |
| dc.subject | complex | en |
| dc.subject | salts | en |
| dc.subject | band | en |
| dc.title | Use of Hydrazine in the Hydrothermal Synthesis of Chalcogenides: the Neutral Framework Material [Mn2SnS4(N2H4)(2)] | en |
| heal.abstract | The reaction system Mn/Sn/S/hydrazine/water at similar to 150 degrees C afforded [Mn2SnS4(N2H4)(2)] (1). The compound has a unique neutral three-dimensional framework with bridging hydrazine ligands and a variety of interconnectivity modes between MnL6 (L = N, S) octahedra. The complex structure of 1 leads to strong antiferromagnetic interactions between the Mn2+ centers and ordering at similar to 41 K. The stabilization of 1 underscores the high potential of hydrazine to promote the formation of novel chalcogenide materials under solvothermal conditions. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Ic900517u | - |
| heal.identifier.secondary | <Go to ISI>://000266428100023 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/ic900517u | - |
| heal.journalName | Inorg Chem | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2009 | - |
| heal.publisher | American Chemical Society | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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