Triarylmethanol Host Compounds. Synthesis, Crystalline Complex Formation and X-Ray Crystal Structures of Three Inclusion Species

dc.contributor.authorE. Weber,en
dc.contributor.authorK. Skobridis,en
dc.contributor.authorA. Wierigen
dc.contributor.authorI. Goldbergen
dc.date.accessioned2015-11-24T16:51:46Z
dc.date.available2015-11-24T16:51:46Z
dc.identifier.issn0923-0750-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9784
dc.rightsDefault Licence-
dc.subjectCrystalline complex formationen
dc.subjectX-ray structure analysisen
dc.subjecttriarylmethanol hostsen
dc.subjectacetone and amine guestsen
dc.subjecthydrogen bondingen
dc.titleTriarylmethanol Host Compounds. Synthesis, Crystalline Complex Formation and X-Ray Crystal Structures of Three Inclusion Speciesen
heal.abstractA variety of triarylmethanol compounds including benzo condensed and laterally substituted derivatives 1-10 have been prepared and shown to act as crystallinehosts for the inclusion of organic solvents involving protic polar, aprotic dipolar and apolar molecules. The inclusion ability is ratherhigh for aprotic dipolar solvents while protic polarcompounds are only rarely enclathrated. Host 9 is an exception, being also efficient with alcohols and amines. Compound3 displays no inclusion formation under theexperimental conditions. X-ray crystal structures of the inclusion compound 1β‹…acetone (2:1) and of two amineinclusion compounds of host 9 [9β‹… n-propylamine(1:1), 9β‹…di-n-propylamine (1:1)] are reported showing the formation of H-bondedhost-guest associates as the common feature of supramolecular association.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primary10.1023/A:1007960204731-
heal.identifier.secondaryhttp://link.springer.com/article/10.1023%2FA%3A1007960204731-
heal.journalNameJ. Inclus. Phenom. Mol. Recogn. Chem.en
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1997-
heal.publisherKluwer Academic Publishersen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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