Unexpected reduction of vanadium(IV) to vanadium(III) in the presence of the chelate ligands 2,2 '-bipyridine (bpy) and 1,8-hydroxyquinoline (Hquin)

dc.contributor.authorManos, M. J.en
dc.contributor.authorTasiopoulos, A. J.en
dc.contributor.authorRaptopoulou, C.en
dc.contributor.authorTerzis, A.en
dc.contributor.authorWoollins, J. D.en
dc.contributor.authorSlawin, A. M. Z.en
dc.contributor.authorKeramidas, A. D.en
dc.contributor.authorKabanos, T. A.en
dc.date.accessioned2015-11-24T16:51:56Z
dc.date.available2015-11-24T16:51:56Z
dc.identifier.issn1472-7773-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9807
dc.rightsDefault Licence-
dc.subjectethanol solvateen
dc.subjectblood-cellsen
dc.subjectcomplexesen
dc.subjectacetonitrileen
dc.subjecto-2en
dc.titleUnexpected reduction of vanadium(IV) to vanadium(III) in the presence of the chelate ligands 2,2 '-bipyridine (bpy) and 1,8-hydroxyquinoline (Hquin)en
heal.abstractThe structures, NMR spectra and electrochemical properties of the vanadium(III) compounds, cis-[(VCl2)-Cl-III(acac)(bpy)] and [V-III(quin)(3)]. 2CH(3)OH, formed from [(VCl2)-Cl-IV(acac)(2)].0.25CH(2)Cl(2) (Hacac=pentane-2,4-dione) and [(VOCl2)-O-IV(thf)(2)] with bpy and Hquin respectively are described as well as the structure of the catecholate dioxovanadium(V) dimer [Et3NH](2)[VO2(mu -dtbc)](2) (H(2)dtbc=3,5-di-tert-butylcatechol).en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDoi 10.1039/B102095l-
heal.identifier.secondary<Go to ISI>://000168598300003-
heal.identifier.secondaryhttp://pubs.rsc.org/en/content/articlepdf/2001/dt/b102095l-
heal.journalNameJournal of the Chemical Society-Dalton Transactionsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2001-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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