Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn-6(mu(4)-O)(2)](10+) Unit
| dc.contributor.author | Moushi, E. E. | en |
| dc.contributor.author | Tasiopoulos, A. J. | en |
| dc.contributor.author | Manos, M. J. | en |
| dc.date.accessioned | 2015-11-24T16:49:07Z | |
| dc.date.available | 2015-11-24T16:49:07Z | |
| dc.identifier.issn | 1565-3633 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9432 | |
| dc.rights | Default Licence | - |
| dc.subject | water-oxidation | en |
| dc.subject | manganese | en |
| dc.subject | core | en |
| dc.subject | complexes | en |
| dc.subject | relevance | en |
| dc.title | Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn-6(mu(4)-O)(2)](10+) Unit | en |
| heal.abstract | A new 1-D coordination polymer {[Mn6O2(O(2)CMc)(10)(H2O)(4)]center dot 2.5H(2)O}(infinity) (1.2.5H(2)O)(infinity) and the cluster [Mn6O2(O-2(O2CPh)(10) (py)(2)(MeCN)(H2O)]center dot 2MeCN (2.2MeCN) are reported. Both compounds were synthesized by room temperature reactions of [Mn-3(mu(3)-O)(O2CR)(6)(L)(2)(L')] (R = Me, L = L' = py, (1.2.5H(2)O)(infinity); R= Ph, L = py, L' = H2O, 2.2MeCN) in the presence of 3-hydroxymethylpyridine (3hmpH) in acetonitrile. The structures of these complexes are based on hexanuclear mixed-valent manganese carboxylate clusters containing the [Mn4(II)Mn(2)(III)(mu(4)-O)(2)](10+) structural core. (1.2.5H(2)O)(infinity) consists of zigzag chain polymers constructed from [Mn6O2(O2CMe)(10)(H2O)(4)] repeating units linked through acetate ligands, whereas 2.2MeCN comprises a discrete Mn-6-benzoate cluster. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1155/2010/367128 | - |
| heal.identifier.secondary | <Go to ISI>://000279731800001 | - |
| heal.identifier.secondary | http://downloads.hindawi.com/journals/bca/2010/367128.pdf | - |
| heal.journalName | Bioinorg Chem Appl | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2010 | - |
| heal.publisher | Hindawi Publishing Corporation | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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