Miscibility of binary blends of ethylene/norbornene copolymers: Comparison to a lattice cluster theory

dc.contributor.authorBlochowiak, M.en
dc.contributor.authorPakula, T.en
dc.contributor.authorButt, H. J.en
dc.contributor.authorFloudas, G.en
dc.date.accessioned2015-11-24T18:40:30Z
dc.date.available2015-11-24T18:40:30Z
dc.identifier.issn0032-3861-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/17630
dc.rightsDefault Licence-
dc.subjectethylene/norbornene copolymersen
dc.subjectmiscibilityen
dc.subjectblendsen
dc.subjectpolymer blendsen
dc.subjectcycloolefin copolymersen
dc.subjectmodelen
dc.subjectrheologyen
dc.subjectdynamicsen
dc.subjectsystemsen
dc.titleMiscibility of binary blends of ethylene/norbornene copolymers: Comparison to a lattice cluster theoryen
heal.abstractThe mutual miscibility of five binary ethylene/norbomene copolymers of the N(x)E(1-x)/N(y)E(1-y) type where x and y represent the norbornene content in the first and second copolymers, respectively (with x/y of 0.36/0.52, 0.36/0.56, 0.36/0.62, 0.46/0.60 and 0.46/0.66), in five different compositions was studied by rheology and differential scanning calorimetry. Most of the blends do not obey the principle of time-temperature superposition, i.e., they can be considered as thermorheologically complex, and hence immiscible. The experimental data from rheology were compared to a recent lattice cluster theory. The theoretical miscibility diagram correctly predicts the experimental cases for most blend compositions except for the very asymmetric compositions. (c) 2007 Elsevier Ltd. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.polymer.2007.08.015-
heal.identifier.secondary<Go to ISI>://000250076600021-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0032386107007951/1-s2.0-S0032386107007951-main.pdf?_tid=973f850bad0034ff4dce60b49028debf&acdnat=1334220284_a0dbaf8561ee4f05ddc9b54a9661ded9-
heal.journalNamePolymeren
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2007-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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