Reaction of graphite fluoride with NaOH-KOH eutectic

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dc.contributor.authorBourlinos, A. B.en
dc.contributor.authorGeorgakilas, V.en
dc.contributor.authorZboril, R.en
dc.contributor.authorJancik, D.en
dc.contributor.authorKarakassides, M. A.en
dc.contributor.authorStassinopoulos, A.en
dc.contributor.authorAnglos, D.en
dc.contributor.authorGiannelis, E. P.en
dc.date.accessioned2015-11-24T17:37:50Z
dc.date.available2015-11-24T17:37:50Z
dc.identifier.issn0022-1139-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/14409
dc.rightsDefault Licence-
dc.subjectgraphite fluorideen
dc.subjecteutectic naoh-kohen
dc.subjectgraphitizationen
dc.subjectwater-soluble carbonen
dc.subjectfluorescenceen
dc.subjectcarbon morphologyen
dc.subjectcarbon nanotubesen
dc.subjectpyrolysisen
dc.subjectmechanismen
dc.subjectdotsen
dc.subjectionen
dc.titleReaction of graphite fluoride with NaOH-KOH eutecticen
heal.abstractGraphite fluoride has been generally considered chemically inert against strong alkalis under ambient conditions. In the present study we demonstrate that treatment of graphite fluoride with eutectic NaOH-KOH mixture at 250 degrees C induces dramatic structural and textural changes in the solid as evidenced by XRD, FT-IR, Raman, UV-vis absorption and fluorescence and microscopy techniques (TEM, AFM). The reaction proceeds in the molten state leading to water-soluble, graphitized carbon particles which unlike graphite fluoride, adopt a variety of morphologies, like platy, tetragonal, triangular, discoid and spherical. The resulting carbon particles are dispersible in water and fluoresce under UV excitation. (c) 2008 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.jfluchem.2008.05.020-
heal.identifier.secondary<Go to ISI>://000259723000011-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0022113908001504/1-s2.0-S0022113908001504-main.pdf?_tid=65078dd8fca67bca2a01deed85ae4b25&acdnat=1339492963_03d7b3daa075ecb1263d76fea7b8c9e8-
heal.journalNameJournal of Fluorine Chemistryen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2008-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Μηχανικών Επιστήμης Υλικώνel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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