Low-Temperature Synthesis of Perovskite Solids Lanio3, Lacoo3, Lamno3, Via Binuclear Complexes of Compartmental Ligand N,N'-Bis(3-Carboxysalicylidene)Ethylenediamine

dc.contributor.authorSkaribas, S. P.en
dc.contributor.authorPomonis, P. J.en
dc.contributor.authorSdoukos, A. T.en
dc.date.accessioned2015-11-24T16:41:15Z
dc.date.available2015-11-24T16:41:15Z
dc.identifier.issn0959-9428-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8389
dc.rightsDefault Licence-
dc.subjectperovskiteen
dc.subjectlow-temperature synthesisen
dc.subjectbinuclear complexen
dc.subjectmetal-complexesen
dc.subject3-formylsalicylic aciden
dc.subjectmolecular-structureen
dc.subjectcitrate processen
dc.subjectsurface-areaen
dc.subjectschiff-basesen
dc.subjectmononuclearen
dc.subjectcrystalen
dc.subjectoxidesen
dc.titleLow-Temperature Synthesis of Perovskite Solids Lanio3, Lacoo3, Lamno3, Via Binuclear Complexes of Compartmental Ligand N,N'-Bis(3-Carboxysalicylidene)Ethylenediamineen
heal.abstractA new method has been developed for the low-temperature synthesis of perovskite solids LaMO3 where M = Ni, Co, Mn, using binuclear complexes of the ligand N,N'-bis(3-carboxysalicylidene)ethylenediamine (H4fsaen). The thermal decomposition of such complexes was studied using a thermobalance. The solids that formed after thermal treatment from 400 to 1000-degrees-C were characterized by X-ray diffraction. Using this method perovskites LaNiO3, LaCoO3 and LaMnO3 have been synthesized at temperatures of ca. 500-600-degrees-C. The above procedure yields solids with specific surface areas substantially higher than those obtained from ordinary ceramic methods, such as citrate and the nitrate routes.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primary10.1039/JM9910100781-
heal.identifier.secondary<Go to ISI>://A1991GH89900010-
heal.identifier.secondaryhttp://pubs.rsc.org/en/Content/ArticleLanding/1991/JM/jm9910100781-
heal.journalNameJournal of Materials Chemistryen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1991-
heal.publisherRoyal Society of Chemistryen
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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