Low-Temperature Synthesis of Perovskite Solids Lanio3, Lacoo3, Lamno3, Via Binuclear Complexes of Compartmental Ligand N,N'-Bis(3-Carboxysalicylidene)Ethylenediamine
dc.contributor.author | Skaribas, S. P. | en |
dc.contributor.author | Pomonis, P. J. | en |
dc.contributor.author | Sdoukos, A. T. | en |
dc.date.accessioned | 2015-11-24T16:41:15Z | |
dc.date.available | 2015-11-24T16:41:15Z | |
dc.identifier.issn | 0959-9428 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8389 | |
dc.rights | Default Licence | - |
dc.subject | perovskite | en |
dc.subject | low-temperature synthesis | en |
dc.subject | binuclear complex | en |
dc.subject | metal-complexes | en |
dc.subject | 3-formylsalicylic acid | en |
dc.subject | molecular-structure | en |
dc.subject | citrate process | en |
dc.subject | surface-area | en |
dc.subject | schiff-bases | en |
dc.subject | mononuclear | en |
dc.subject | crystal | en |
dc.subject | oxides | en |
dc.title | Low-Temperature Synthesis of Perovskite Solids Lanio3, Lacoo3, Lamno3, Via Binuclear Complexes of Compartmental Ligand N,N'-Bis(3-Carboxysalicylidene)Ethylenediamine | en |
heal.abstract | A new method has been developed for the low-temperature synthesis of perovskite solids LaMO3 where M = Ni, Co, Mn, using binuclear complexes of the ligand N,N'-bis(3-carboxysalicylidene)ethylenediamine (H4fsaen). The thermal decomposition of such complexes was studied using a thermobalance. The solids that formed after thermal treatment from 400 to 1000-degrees-C were characterized by X-ray diffraction. Using this method perovskites LaNiO3, LaCoO3 and LaMnO3 have been synthesized at temperatures of ca. 500-600-degrees-C. The above procedure yields solids with specific surface areas substantially higher than those obtained from ordinary ceramic methods, such as citrate and the nitrate routes. | en |
heal.access | campus | - |
heal.fullTextAvailability | TRUE | - |
heal.identifier.primary | 10.1039/JM9910100781 | - |
heal.identifier.secondary | <Go to ISI>://A1991GH89900010 | - |
heal.identifier.secondary | http://pubs.rsc.org/en/Content/ArticleLanding/1991/JM/jm9910100781 | - |
heal.journalName | Journal of Materials Chemistry | en |
heal.journalType | peer reviewed | - |
heal.language | en | - |
heal.publicationDate | 1991 | - |
heal.publisher | Royal Society of Chemistry | en |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.type | journalArticle | - |
heal.type.el | Άρθρο Περιοδικού | el |
heal.type.en | Journal article | en |
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