Interactions of trivalent lanthanide cations with tetradentate Schiff bases. Synthesis and characterization of lanthanide(III) complexes with N,N '-bis(pyridin-2-ylmethylene)benzene-1,2-diamine

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dc.contributor.authorTsiouri, M.en
dc.contributor.authorPlakatouras, J. C.en
dc.contributor.authorGaroufis, A.en
dc.contributor.authorNastopoulos, V.en
dc.contributor.authorHadjiliadis, N.en
dc.date.accessioned2015-11-24T16:40:21Z
dc.date.available2015-11-24T16:40:21Z
dc.identifier.issn1387-7003-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8265
dc.rightsDefault Licence-
dc.subjectcrystal structureen
dc.subjectlanthanide complexesen
dc.subjectschiff basesen
dc.subject10-coordinateen
dc.subjectmri contrast reagentsen
dc.subject6-nitrogen-donor macrocyclic liganden
dc.subjectray crystal-structureen
dc.subjecteuropium(iii)en
dc.subjectyttrium(iii)en
dc.subjectluminescenceen
dc.titleInteractions of trivalent lanthanide cations with tetradentate Schiff bases. Synthesis and characterization of lanthanide(III) complexes with N,N '-bis(pyridin-2-ylmethylene)benzene-1,2-diamineen
heal.abstractThe novel lanthanide(III) complexes [La(NO(3))(3)(H(2)O)L] 1, and [Ln(NO(3))(3)L] (Ln=Pr 2, Sm 3, Gd 4) where L=N,N'-bis(pyridin-2-ylmethylene)benzene-1,2-diamine, have been obtained by direct reaction of the Schiff base ligand and the corresponding hydrated lanthanide(III) nitrates in methanol. All complexes were characterized spectroscopically and thermogravimetrically. Complex 3 was also characterized with crystallographic studies. In the molecular structure of 3, Sm(III) is surrounded by all four nitrogen atoms of the Schiff base and six oxygen atoms belonging to three bidentate chelating nitrato ligands. (C) 2002 Elsevier Science B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://000178648800026-
heal.identifier.secondaryhttp://ac.els-cdn.com/S1387700302005701/1-s2.0-S1387700302005701-main.pdf?_tid=98b0e76def86d12d777c888df8808407&acdnat=1333029347_7c5c0a6d9c2a7ee4021d52bc371a2c15-
heal.journalNameInorganic Chemistry Communicationsen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2002-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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