Insertion of Functional Groups into a Nd3+ Metal-Organic Framework via Single-Crystal-to-Single-Crystal Coordinating Solvent Exchange
| dc.contributor.author | Manos, M. J. | en |
| dc.contributor.author | Kyprianidou, E. J. | en |
| dc.contributor.author | Papaefstathiou, G. S. | en |
| dc.contributor.author | Tasiopoulos, A. J. | en |
| dc.date.accessioned | 2015-11-24T16:40:08Z | |
| dc.date.available | 2015-11-24T16:40:08Z | |
| dc.identifier.issn | 0020-1669 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8236 | |
| dc.rights | Default Licence | - |
| dc.subject | design | en |
| dc.subject | state | en |
| dc.title | Insertion of Functional Groups into a Nd3+ Metal-Organic Framework via Single-Crystal-to-Single-Crystal Coordinating Solvent Exchange | en |
| heal.abstract | Single-crystal-to-single-crystal (SCSC) transformations represent some of the most fascinating phenomena in chemistry. They are not only intriguing from a basic science point of view but also provide a means to modify or tune the properties of the materials via the postsynthetic introduction of suitable guest molecules or organic functional groups into their structures. Here, we describe UCY-2, a new flexible Nd3+ metal-organic framework (MOF), which exhibits a unique capability to undergo a plethora of SCSC transformations with some of them being very uncommon. These structural alterations involve the replacement of coordinating solvent molecules of UCY-2 by terminally ligating solvents and organic ligands with multiple functional groups including -OH, -SH, -NH-, and -NH2 or their combinations, chelating ligands, anions, and two different organic compounds. The SCSC coordinating solvent exchange is thus demonstrated as a powerful method for the functionalization of MOFs. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Ic3005085 | - |
| heal.identifier.secondary | <Go to ISI>://000304728500038 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/ic3005085 | - |
| heal.journalName | Inorg Chem | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2012 | - |
| heal.publisher | American Chemical Society | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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