Synthesis, structural characterisation and study of mercury(II) iodide complexes with the heterocyclic thioamides pyridine-2-thione (pytH) and thiazolidine-2-thione (tzdtH). Crystal structures of [HgI2(pytH)(2)] and [HgI2(tzdtH)(2)]
| dc.contributor.author | Hadjikakou, S. K. | en |
| dc.contributor.author | Xanthopoulou, M. N. | en |
| dc.contributor.author | Hadjiliadis, N. | en |
| dc.contributor.author | Kubicki, M. | en |
| dc.date.accessioned | 2015-11-24T16:49:40Z | |
| dc.date.available | 2015-11-24T16:49:40Z | |
| dc.identifier.issn | 1205-6685 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9516 | |
| dc.rights | Default Licence | - |
| dc.subject | mercury(ii) complexes | en |
| dc.subject | s- ligands | en |
| dc.subject | pyrimidine-2-thione | en |
| dc.subject | thiazoline-2-thione | en |
| dc.subject | crystal structures | en |
| dc.subject | photo-decomposition | en |
| dc.subject | group-12 metals | en |
| dc.subject | electrochemical synthesis | en |
| dc.subject | photoredox chemistry | en |
| dc.subject | 1/2 complexes | en |
| dc.subject | part 3 | en |
| dc.subject | 160 k | en |
| dc.subject | thiones | en |
| dc.subject | halides | en |
| dc.subject | 1,3-thiazolidine-2-thione | en |
| dc.subject | triphenylphosphine | en |
| dc.title | Synthesis, structural characterisation and study of mercury(II) iodide complexes with the heterocyclic thioamides pyridine-2-thione (pytH) and thiazolidine-2-thione (tzdtH). Crystal structures of [HgI2(pytH)(2)] and [HgI2(tzdtH)(2)] | en |
| heal.abstract | Direct reaction of mercury(H) iodide with pyridine-2-thione (pytH) or thiazoline-2-thione (tzdtH) in a 1:2 molar ratio, results in the formation of [HgI2(PytH)(2)] (1) and [HgI2(tzdtH)(2)] (2), respectively. The complexes have been characterised by elemental analysis and FT-Raman, FT-IR, UV-Vis and H-1, Hg-119-NMR spectroscopy. Crystal structures Of [bis (pyridine-2-thione) di-iodo mercury(II)] (1) and [bis(thiazolidine-2-thione) di-iodo mercury(II)] (2) complexes have been determined by x-ray diffraction at 100(1) K and 293(2) K respectively. Molecules (1) and (2) are monomers with a tetrahedral geometry around the metal ion with two iodine and two sulphur atoms co-ordinated to mercury(II). An extended intermolecular linkage via N-(HI)-I-... or N-(HS)-S-... interactions leads to an one dimensional extended lattice structure in case of complex (2), and a three dimensional extended network in case of complex (1). The light sensitivity of the complex (1) is also evaluated. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.secondary | <Go to ISI>://000183264400008 | - |
| heal.journalName | Canadian Journal of Analytical Sciences and Spectroscopy | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2003 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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