Palladium(II) complexes of 4-formylantipyrine N(3)-substituted thiosemicarbazones: first example of X-ray crystal structure and description of bonding properties
| dc.contributor.author | Yadav, P. N. | en |
| dc.contributor.author | Demertzis, M. A. | en |
| dc.contributor.author | Kovala-Demertzi, D. | en |
| dc.contributor.author | Skoulika, S. | en |
| dc.contributor.author | West, D. X. | en |
| dc.date.accessioned | 2015-11-24T16:43:57Z | |
| dc.date.available | 2015-11-24T16:43:57Z | |
| dc.identifier.issn | 0020-1693 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/8757 | |
| dc.rights | Default Licence | - |
| dc.subject | antipyrine | en |
| dc.subject | thiosemicarbazone | en |
| dc.subject | palladium | en |
| dc.subject | crystal structure | en |
| dc.subject | spectral study | en |
| dc.subject | electrochemistry | en |
| dc.subject | pyridine n-oxides | en |
| dc.subject | copper(ii) complexes | en |
| dc.subject | heterocyclic thiosemicarbazones | en |
| dc.subject | spectral properties | en |
| dc.subject | n(4)-substituted thiosemicarbazones | en |
| dc.subject | zinc(ii) complexes | en |
| dc.subject | antitumor-activity | en |
| dc.subject | metal-complexes | en |
| dc.subject | platinum(ii) complexes | en |
| dc.subject | 2-acetyl pyridine | en |
| dc.title | Palladium(II) complexes of 4-formylantipyrine N(3)-substituted thiosemicarbazones: first example of X-ray crystal structure and description of bonding properties | en |
| heal.abstract | Reaction of 4-formylantipyrine with thiosemicarbazide, N(3)-methylthiosemicarbazide and N(3)-ethylthiosemicarbazide produced the expected thiosemicarbazones, 1, 2 and 3. The three thiosemicarbazones were then reacted with K2PdCl4 to produce [Pd(NS)(2)] complexes, 4, 5, and 6, respectively, with coordination by the imine nitrogen and thiolate sulfur of the anionic thiosemicarbazone moiety. The thiosemicarbazones and their palladium complexes have been characterized by spectral IR, UV-Vis and H-1, C-13 NMR and electrochemical techniques. The crystal structure of 6 has been obtained and found to be highly symmetrical with a trans arrangement of the two bidentate ligands. (K) (C) 2003 Elsevier Science B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1016/S0020-1693(03)00087-2 | - |
| heal.identifier.secondary | <Go to ISI>://000183673100005 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0020169303000872/1-s2.0-S0020169303000872-main.pdf?_tid=22936bf04666732d0c14c03bf843b9ea&acdnat=1333028996_85f38918507ae0db3c79b23edc2b672d | - |
| heal.journalName | Inorganica Chimica Acta | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2003 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
Αρχεία
Φάκελος/Πακέτο αδειών
1 - 1 of 1
Φόρτωση...
- Ονομα:
- license.txt
- Μέγεθος:
- 1.74 KB
- Μορφότυπο:
- Item-specific license agreed upon to submission
- Περιγραφή: