Anion-Induced Formation of Lanthanide-Organic Chains From 3D Framework Solids. Anion Exchange in a Crystal-to-Crystal Manner
| dc.contributor.author | Michaelides, A. | en |
| dc.contributor.author | Skoulika, S. | en |
| dc.date.accessioned | 2015-11-24T16:50:11Z | |
| dc.date.available | 2015-11-24T16:50:11Z | |
| dc.identifier.issn | 1528-7483 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9577 | |
| dc.rights | Default Licence | - |
| dc.subject | coordination polymers | en |
| dc.subject | adipate frameworks | en |
| dc.subject | thermal-properties | en |
| dc.subject | complexes | en |
| dc.subject | solvent | en |
| dc.subject | ligand | en |
| dc.subject | chemistry | en |
| dc.subject | state | en |
| dc.subject | transformations | en |
| dc.subject | functionalities | en |
| dc.title | Anion-Induced Formation of Lanthanide-Organic Chains From 3D Framework Solids. Anion Exchange in a Crystal-to-Crystal Manner | en |
| heal.abstract | A water-mediated transformation reversibly converts the neutral 3D microporous coordination polymers [Ln(2)(adipate)(3)(-)(H(2)O)(4)]center dot 6H(2)O (Ln(3+) = Pr(3+)) and [Ln(2)(adipate)(3)(H(2)O)(4)]xH(2)O (Ln(3+) = Gd(3+), Sm(3+)), into the ionic 1D polymer [Ln(adipate)(H(2)O)(5)]XH(2)O (with X = NO(3)(-), Cl(-) and Ln(3+) = Pr(3+), Gd(3+), Sm(3+)). The 1D polymer consists of positively charged hydrogen-bonded lanthanide-adipate chains enclathrating NO(3)(-) or Cl(-) anions acting as templates. The hydrogen bonds linking the chains between them are so strong, that it is possible to exchange NO(3)(-) for Cl(-) and vice versa in a crystal-to-crystal manner. The anion exchange reactions were directly observed oil crystals by Using Raman microprobe spectroscopy, single-crystal X-ray diffraction, and scanning electron microscopy. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | Doi 10.1021/Cg801138e | - |
| heal.identifier.secondary | <Go to ISI>://000265892200005 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/abs/10.1021/cg801138e | - |
| heal.journalName | Crystal Growth & Design | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2009 | - |
| heal.publisher | American Chemical Society | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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