Silicon analogues of triarylmethanol hosts. Inclusion properties and host-guest structures: A comparative study

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dc.contributor.authorWeber, E.en
dc.contributor.authorSeichter, W.en
dc.contributor.authorSkobridis, K.en
dc.contributor.authorAlivertis, D.en
dc.contributor.authorTheodorou, V.en
dc.contributor.authorBombicz, P.en
dc.contributor.authorCsoregh, I.en
dc.date.accessioned2015-11-24T16:47:17Z
dc.date.available2015-11-24T16:47:17Z
dc.identifier.issn0923-0750-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/9160
dc.rightsDefault Licence-
dc.subjectcrystalline inclusion chemistryen
dc.subjectinclusion compoundsen
dc.subjectisostructurality behaviouren
dc.subjectsupramolecular interactionsen
dc.subjecttriarylmethanol/triarylsilanol hostsen
dc.subjectx-ray structure determinationen
dc.subjectcrystalline complex-formationen
dc.subjectdimethyl-sulfoxideen
dc.subjectorganic-chemistryen
dc.subjectthermal-analysisen
dc.subjectdiol hostsen
dc.subjecttriphenylmethanolen
dc.subjecttriphenylsilanolen
dc.subjectisostructuralityen
dc.subjectmoleculesen
dc.subjectpatternsen
dc.titleSilicon analogues of triarylmethanol hosts. Inclusion properties and host-guest structures: A comparative studyen
heal.abstractThe simple triarylmethanol hosts, 2 and 4, and their silicon analogues, I and 3, have been studied for comparison of the formation of crystalline inclusion compounds. Clathrate formation experiments showed that replacement of the carbinol C atoms in 2 and 4 by Si atoms to give I and 3 resulted in a distinct increase of the capability to form inclusion compounds with organic guests, in particular with alcohols. Moreover, the naphthyl derivatives are much more efficient than the phenyl species, irrespective of the carbinol and silanol features. In order to investigate and compare the guest recognition modes and packing relations of hosts 1-4 in their crystalline inclusion compounds, I I selected co-crystals, namely 1-DMSO (2:1), 3-EtOH (1: 1), 3-i-PrOH (1: 1), 3-acetone (1: 1), 3-DMSO (1: 1), 3-THF (1: 1), 3-piperidine (1: 1), 4-acetone (1: 1), 4-DMSO (1: 1), 4-1,4-dioxane (1: 1) and 4-benzene (1: 1), were studied by X-ray diffraction from single crystals. The survey contains additional I I crystal structures from the literature and provides a detailed discussion of isostructurality relationships.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1007/s10847-005-9029-2-
heal.identifier.secondary<Go to ISI>://000239432200016-
heal.identifier.secondaryhttp://www.springerlink.com/content/m617r510813v2140/fulltext.pdf-
heal.journalNameJournal of Inclusion Phenomena and Macrocyclic Chemistryen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2006-
heal.publisherSpringeren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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