Temperature dependence of the Mossbauer parameters in the iron(II) ethyl phosphonate Fe(II)(PO3C2H5)center dot H2O
dc.contributor.author | Palvadeau, P. | en |
dc.contributor.author | Queignec, M. | en |
dc.contributor.author | Bujoli, B. | en |
dc.contributor.author | Papaefthymiou, V. | en |
dc.contributor.author | Bakas, T. | en |
dc.date.accessioned | 2015-11-24T18:34:23Z | |
dc.date.available | 2015-11-24T18:34:23Z | |
dc.identifier.issn | 0025-5408 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/16926 | |
dc.rights | Default Licence | - |
dc.subject | inorganic compounds | en |
dc.subject | layered compounds | en |
dc.subject | infrared spectroscopy | en |
dc.subject | mossbauer spectroscopy | en |
dc.title | Temperature dependence of the Mossbauer parameters in the iron(II) ethyl phosphonate Fe(II)(PO3C2H5)center dot H2O | en |
heal.abstract | Fe-57 Mossbauer measurements have been performed on the lamellar iron (II) ethylphosphonate Fe(II)(C2H5PO3). H2O. Mossbauer parameters have been studied as a function of temperature in the paramagnetic state (above 28 K). In the temperature range 150-200 K this compound has been found to undergo a phase transition resulting in a discontinuity in the quadrupole splitting Delta E. This unusual behavior was ascribed to a structural change and not to a transition from an ordered to a quasi-liquid state of the water molecule and/or CH2-CH3 moieties, Results of a preliminary infrared study supports this hypothesis. | en |
heal.access | campus | - |
heal.fullTextAvailability | TRUE | - |
heal.identifier.secondary | <Go to ISI>://A1996UK36200012 | - |
heal.identifier.secondary | http://ac.els-cdn.com/S0025540896000372/1-s2.0-S0025540896000372-main.pdf?_tid=b6ed9232f0eeef1ac0b58672909fe619&acdnat=1334136316_1abcbdb0e41bf211563831f9e6438666 | - |
heal.journalName | Materials Research Bulletin | en |
heal.journalType | peer reviewed | - |
heal.language | en | - |
heal.publicationDate | 1996 | - |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
heal.type | journalArticle | - |
heal.type.el | Άρθρο Περιοδικού | el |
heal.type.en | Journal article | en |
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