A high-sensitive spectrofluorimetric method for the determination of micromolar concentrations of iron(III) in bovine liver with 4-hydroxyquinoline

dc.contributor.authorRagos, G. C.en
dc.contributor.authorDemertzis, M. A.en
dc.contributor.authorIssopoulos, P. B.en
dc.date.accessioned2015-11-24T16:55:14Z
dc.date.available2015-11-24T16:55:14Z
dc.identifier.issn0014-827X-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/10279
dc.rightsDefault Licence-
dc.subjectspectrofluorimetric determinationen
dc.subjectironen
dc.subjectliveren
dc.subject4-hydroxyquinolineen
dc.subjecttrace-elementsen
dc.subjectspectrometryen
dc.subjectdigestionen
dc.subjecttissuesen
dc.subjectaciden
dc.titleA high-sensitive spectrofluorimetric method for the determination of micromolar concentrations of iron(III) in bovine liver with 4-hydroxyquinolineen
heal.abstractA new sensitive, rapid and accurate spectrofluorimetric method, suitable for the determination of micromolar concentrations of iron(III) in bovine liver, using 4-hydroxyquinoline (4-HQ) in an alkaline medium (KOH 2.0 x 10(-2) mol/l) as fluorescent agent, is described. The fluorescence intensity of the working solutions was measured at lambda(ex) 305 nm and lambda(em) 380 nm. The observed decrease of the above mentioned intensity was mainly due to the quenching, caused by the interaction between the iron(III) to be analysed and the potentially fluorescent 4-HQ. The accuracy and the precision of the proposed method, after an experimental investigation, could be considered as very satisfactory. Potassium fluoride and triethylenetetramine solutions were successfully used for the masking of those metal cations existing in the bovine liver which interfere seriously with the determination of iron(III). (C) 1998 Elsevier Science S.A. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.secondary<Go to ISI>://000078672900014-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0014827X98000706/1-s2.0-S0014827X98000706-main.pdf?_tid=f68b0e63ebeaf3e633beb6727095a12f&acdnat=1333028897_672ebc4cac44232ce6286eaf72b74753-
heal.journalNameFarmacoen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate1998-
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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