The lifetime of the perpendicular minimum of cis-stilbene observed by dissociative intense-laser field ionization
| dc.contributor.author | Fuss, W. | en |
| dc.contributor.author | Kosmidis, C. | en |
| dc.contributor.author | Schmid, W. E. | en |
| dc.contributor.author | Trushin, S. A. | en |
| dc.date.accessioned | 2015-11-24T18:33:28Z | |
| dc.date.available | 2015-11-24T18:33:28Z | |
| dc.identifier.issn | 0009-2614 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/16738 | |
| dc.rights | Default Licence | - |
| dc.subject | transition-state dynamics | en |
| dc.subject | conical intersections | en |
| dc.subject | vibrational coherence | en |
| dc.subject | charge-transfer | en |
| dc.subject | ab-initio | en |
| dc.subject | photoisomerization | en |
| dc.subject | isomerization | en |
| dc.subject | picosecond | en |
| dc.subject | dependence | en |
| dc.subject | molecules | en |
| dc.title | The lifetime of the perpendicular minimum of cis-stilbene observed by dissociative intense-laser field ionization | en |
| heal.abstract | Cis-stilbene was excited by one photon at 270 nm in the gas phase and then probed by ionization at infrared wavelengths (810 and 2100 nm), recording the delay-time dependent mass spectra. We found not only a decay of 300 fs, previously assigned to departure from the fluorescent region, but also a second time constant (160 A), probably representing departure from the 'perpendicular minimum' (excited state with twisted ethene part). In addition, two coherent oscillations (periods 140 and approximate to600 fs) were found in the 300-fs window. We discuss their implications for the initial motion and point out the importance of vibronic interaction of excited states. (C) 2004 Elsevier B.V. All rights reserved. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | DOI 10.1016/j.cplett.2003.12.114 | - |
| heal.identifier.secondary | <Go to ISI>://000189087800016 | - |
| heal.identifier.secondary | http://ac.els-cdn.com/S0009261404000168/1-s2.0-S0009261404000168-main.pdf?_tid=1bfae30203b01668c32eee641bd0d3f2&acdnat=1334229093_8b7c6c991e8a0d04202deaf63d78afad | - |
| heal.journalName | Chemical Physics Letters | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2004 | - |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Επιστημών και Τεχνολογιών. Τμήμα Βιολογικών Εφαρμογών και Τεχνολογιών | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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