Crystal structure and solid-state reactivity of a Cd(II) polymeric complex with acetylenedicarboxylic acid
| dc.contributor.author | Skoulika, S. | en |
| dc.contributor.author | Dallas, P. | en |
| dc.contributor.author | Siskos, M. G. | en |
| dc.contributor.author | Deligiannakis, Y. | en |
| dc.contributor.author | Michaelides, A. | en |
| dc.date.accessioned | 2015-11-24T16:55:05Z | |
| dc.date.available | 2015-11-24T16:55:05Z | |
| dc.identifier.issn | 0897-4756 | - |
| dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10250 | |
| dc.rights | Default Licence | - |
| dc.subject | coordination polymer | en |
| dc.subject | hydrothermal reactions | en |
| dc.subject | frameworks | en |
| dc.subject | decarboxylation | en |
| dc.subject | spectroscopy | en |
| dc.subject | derivatives | en |
| dc.subject | copper(ii) | en |
| dc.subject | transition | en |
| dc.subject | molecules | en |
| dc.subject | chemistry | en |
| dc.title | Crystal structure and solid-state reactivity of a Cd(II) polymeric complex with acetylenedicarboxylic acid | en |
| heal.abstract | The novel one-dimensional coordination polymer [Cd(ADC)(H2O)(3)] H2O, where ADC(2-) = acetylenedicarboxylate dianion, was synthesized and characterized by single-crystal X-ray diffraction. The titled compound crystallizes in the monoclinic system, P2(1)/n, a = 6.908(1) Angstrom, b = 7.946(1) Angstrom, c = 16.390(1) Angstrom, beta = 100.21(1)degrees, V = 885.4(2) Angstrom(3), and Z = 4. The structure is made up of metal-organic chains linked by hydrogen bonds to form channels along the b axis. The carbon-carbon triple bonds are in close proximity (3.27 Angstrom) along the a axis. This induces, upon heating, polymerization with formation of conjugated polycarboxylic chains. Detailed EPR studies have been performed in order to understand the polymerization process. | en |
| heal.access | campus | - |
| heal.fullTextAvailability | TRUE | - |
| heal.identifier.primary | 10.1021/cm034666e | - |
| heal.identifier.secondary | <Go to ISI>://000186886600008 | - |
| heal.identifier.secondary | http://pubs.acs.org/doi/pdfplus/10.1021/cm034666e | - |
| heal.journalName | Chemistry of Materials | en |
| heal.journalType | peer reviewed | - |
| heal.language | en | - |
| heal.publicationDate | 2003 | - |
| heal.publisher | American Chemical Society | en |
| heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
| heal.type | journalArticle | - |
| heal.type.el | Άρθρο Περιοδικού | el |
| heal.type.en | Journal article | en |
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