Ring-Enlarged Dibenzo-Crown-6 Ethers. Cation Binding and X-Ray Crystal Structure of Dibenzo-22-Crown-6
dc.contributor.author | M. Ouchi, | en |
dc.contributor.author | T. Araki, | en |
dc.contributor.author | T. Hakushi, | en |
dc.contributor.author | M. E. Sobhia, | en |
dc.contributor.author | K. K. Chacko, | en |
dc.contributor.author | K. Skobridis | en |
dc.contributor.author | E. Weber | en |
dc.date.accessioned | 2015-11-24T16:46:31Z | |
dc.date.available | 2015-11-24T16:46:31Z | |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/9080 | |
dc.rights | Default Licence | - |
dc.title | Ring-Enlarged Dibenzo-Crown-6 Ethers. Cation Binding and X-Ray Crystal Structure of Dibenzo-22-Crown-6 | en |
heal.abstract | The cation binding of dibenzo-20-crown-6 (2) and dibenzo-22-crown-6 (3) are determined by quantitative solvent extraction study. Compound 3 shows high Tl+/K+ and Tl+/Rb+ selectivity. The crystal structure of 3 is reported. Crystal data: monoclinic (P21/c), a = 7.328(1), b = 17.395(4), c = 8.939(1) Γ…, Ξ² = 102.78(1)Β°, Z = 2, R = 0.049 for 2122 reflections. The macrocycle shows a crystallographic center of symmetry with elliptical arrangement of the heteroatoms stabilized by possible C-HΒ·Β·Β·O dipolar attractions. | en |
heal.access | campus | - |
heal.fullTextAvailability | TRUE | - |
heal.identifier.primary | http://dx.doi.org/10.1246/bcsj.66.2309 | - |
heal.identifier.secondary | https://www.jstage.jst.go.jp/article/bcsj/66/8/66_8_2309/_article | - |
heal.journalName | Bulletin of the Chemical Society of Japan | en |
heal.journalType | peer reviewed | - |
heal.language | en | - |
heal.publicationDate | 1993 | - |
heal.publisher | The Chemical Society of Japan | en |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.type | journalArticle | - |
heal.type.el | Άρθρο Περιοδικού | el |
heal.type.en | Journal article | en |
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