Ion-pair single-drop microextraction versus phase-transfer catalytic extraction for the gas chromatographic determination of phenols as tosylated derivatives

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dc.contributor.authorFiamegos, Y. C.en
dc.contributor.authorKefala, A. P.en
dc.contributor.authorStalikas, C. D.en
dc.date.accessioned2015-11-24T16:40:37Z
dc.date.available2015-11-24T16:40:37Z
dc.identifier.issn0021-9673-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8294
dc.rightsDefault Licence-
dc.subjectphenolsen
dc.subjectp-toluenesulfonyl chlorideen
dc.subjectphase-transfer catalysisen
dc.subjection-pairen
dc.subjectsingle-drop microextractionen
dc.subjectpreconcentrationen
dc.subjectderivatizationen
dc.subjectmass-spectrometric detectionen
dc.subjectwater samplesen
dc.subjectliquid-chromatographyen
dc.subjectspectrophotometric determinationen
dc.subjectendocrine disruptionen
dc.subjecttrace concentrationsen
dc.subjectselective detectionen
dc.subjectderivatizationen
dc.subjectionizationen
dc.subjectchlorophenolsen
dc.titleIon-pair single-drop microextraction versus phase-transfer catalytic extraction for the gas chromatographic determination of phenols as tosylated derivativesen
heal.abstractThe environmental fate of phenols represents a diachronic scientific consideration mainly due to their high toxicity and diverse physicochemical properties rendering them difficult to be analyzed as unity. Ion-pair-assisted extraction and microextraction techniques in association with a dedicated derivatization reaction are possible to lead to enhanced selectivity and sensitivity in gas chromatography. Phase-transfer catalytic liquid-liquid extraction-derivatization and ion-pair-assisted single-drop microextraction with in-drop derivatization are successfully employed for the analysis of 15 phenolic compounds. The analytes that react at room temperature with p-toluenesulfonyl chloride into the bulk of the organic phase are subsequently determined by GC-MS in selective-ion monitoring mode. Aiming at maximizing the derivatization yields obtained from the 15 analytes in a reasonable time period, the optimum experimental parameters were established along with the figures of merit of the methods. The limits of detection ranged from 0.48 to 1.5 ng/ml and from 0.20 to 0.28 ng/ml respectively, while the limits of quantitation ranged from 1.4 to 4.5 ng/ml and from 0.59 to 0.84 ng/ml for the two methods with the techniques under study. The overall procedure presented satisfactory analytical features with the liquid-liquid extraction protocol being easier to carry out while the single-drop one, presented higher sensitivity and significant reduction of the organic solvent employed. By comparison with other methods for the analysis of phenols, the proposed methods exhibit adequately low detection limits, good precision, short derivatization time and low solvent, sample and reagent consumption. (C) 2008 Elsevier B.V. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.chroma.2008.03.010-
heal.identifier.secondary<Go to ISI>://000255848600007-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0021967308004500/1-s2.0-S0021967308004500-main.pdf?_tid=32640d511e9d0a0c7f31ec5c2e080562&acdnat=1333040709_e55d832472cc8a9643aa6153bf572f2f-
heal.journalNameJournal of Chromatography Aen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2008-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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