Eight-coordination in nitrato manganese(II) complexes with tetradentate di-Schiff bases derived from 2-pyridyl ketones: preparation, characterization and catalytic activity for alkene epoxidation
dc.contributor.author | Louloudi, M. | en |
dc.contributor.author | Nastopoulos, V. | en |
dc.contributor.author | Gourbatsis, S. | en |
dc.contributor.author | Perlepes, S. P. | en |
dc.contributor.author | Hadjiliadis, N. | en |
dc.date.accessioned | 2015-11-24T16:57:31Z | |
dc.date.available | 2015-11-24T16:57:31Z | |
dc.identifier.issn | 1387-7003 | - |
dc.identifier.uri | https://olympias.lib.uoi.gr/jspui/handle/123456789/10587 | |
dc.rights | Default Licence | - |
dc.subject | crystal structures | en |
dc.subject | eight-coordinate manganese(ii) complexes | en |
dc.subject | n-4 tetradentate schiff bases | en |
dc.subject | nitrate complexes | en |
dc.subject | dodecahedral geometry | en |
dc.subject | catalysts for alkene epoxidation | en |
dc.subject | hydrocarbons | en |
dc.subject | oxidation | en |
dc.title | Eight-coordination in nitrato manganese(II) complexes with tetradentate di-Schiff bases derived from 2-pyridyl ketones: preparation, characterization and catalytic activity for alkene epoxidation | en |
heal.abstract | The reactions of Mn(NO3)(2). 6H(2)O with the tetradentate Schiff bases N,N'-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine (L-A) and N,N'-bis[1-(pyridin-2-yl)benzylidene]ethane-1,2-diamine (L-B) afforded the novel eight-coordinate complexes [Mn(NO3)(2)(L-A)] (1) and [Mn(NO3)(2)(L-B)] (2), which have a distorted dodecahedral coordination geometry. The catalytic activity of 1 and 2 for alkene epoxidation is reported and discussed. (C) 1999 Elsevier Science S.A. All rights reserved. | en |
heal.access | campus | - |
heal.fullTextAvailability | TRUE | - |
heal.identifier.primary | Doi 10.1016/S1387-7003(99)00127-6 | - |
heal.identifier.secondary | <Go to ISI>://000083582600011 | - |
heal.identifier.secondary | http://ac.els-cdn.com/S1387700399001276/1-s2.0-S1387700399001276-main.pdf?_tid=a1017bc0-362e-11e3-bcb3-00000aacb360&acdnat=1381906144_1da402a063dadce181a8a954a326f4c5 | - |
heal.journalName | Inorganic Chemistry Communications | en |
heal.journalType | peer reviewed | - |
heal.language | en | - |
heal.publicationDate | 1999 | - |
heal.publisher | Elsevier | en |
heal.recordProvider | Πανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείας | el |
heal.type | journalArticle | - |
heal.type.el | Άρθρο Περιοδικού | el |
heal.type.en | Journal article | en |
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