New type dithiolene complex based on 4,5-(1,4-dioxane-2,3-diyldithio)-1,3-dithiol ligand: Synthesis, experimental and theoretical investigation

dc.contributor.authorSofas, G.en
dc.contributor.authorPsaroudakis, N.en
dc.contributor.authorManos, M. J.en
dc.contributor.authorTasiopoulos, A. J.en
dc.contributor.authorLiakos, D. G.en
dc.contributor.authorMousdis, G. A.en
dc.date.accessioned2015-11-24T16:42:41Z
dc.date.available2015-11-24T16:42:41Z
dc.identifier.issn0277-5387-
dc.identifier.urihttps://olympias.lib.uoi.gr/jspui/handle/123456789/8581
dc.rightsDefault Licence-
dc.subjectdithiolene complexesen
dc.subjectir and raman spectraen
dc.subjectab initio calculationsen
dc.subjectcrystal structureen
dc.subjectcyclic voltammetryen
dc.subjectmulti-sulfur 1,2-dithioleneen
dc.subjectnear-ir absorptionen
dc.subjectnickel-complexesen
dc.subjectdensityen
dc.subjecttransitionen
dc.subjectnien
dc.subjectpden
dc.titleNew type dithiolene complex based on 4,5-(1,4-dioxane-2,3-diyldithio)-1,3-dithiol ligand: Synthesis, experimental and theoretical investigationen
heal.abstractA new Nickel complex with an extended multisulfur dithiolene ligand Ni(edodddt)(2) (edodddt = 2,3,4 alpha,8 alpha-tetrahydro-dithiine [2,3-b] [1,4] dioxo-6,7-dithiolene) has been synthesized and characterized by electrochemical measurements, IR, UV-Vis and NMR spectroscopy. Its crystal structure was resolved by X-ray diffraction on a single crystal. DFT calculations were made in order to compare the results with the experimental findings and gain an insight of the properties of this new dithiolene complex. (c) 2009 Elsevier Ltd. All rights reserved.en
heal.accesscampus-
heal.fullTextAvailabilityTRUE-
heal.identifier.primaryDOI 10.1016/j.poly.2009.05.031-
heal.identifier.secondary<Go to ISI>://000271144200026-
heal.identifier.secondaryhttp://ac.els-cdn.com/S0277538709002666/1-s2.0-S0277538709002666-main.pdf?_tid=704f48ce-3636-11e3-a0e8-00000aacb361&acdnat=1381909499_9b7498af9083dd174612192caa7a0aac-
heal.journalNamePolyhedronen
heal.journalTypepeer reviewed-
heal.languageen-
heal.publicationDate2009-
heal.publisherElsevieren
heal.recordProviderΠανεπιστήμιο Ιωαννίνων. Σχολή Θετικών Επιστημών. Τμήμα Χημείαςel
heal.typejournalArticle-
heal.type.elΆρθρο Περιοδικούel
heal.type.enJournal articleen

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